A review with 64 refs. is presented on the mixed valence chem. of analogs of the Creutz-Taube ion. Starting from the Creutz-Taube ion as the prototype of a mol.-bridged mixed-valent complex, a no. of related systems are presented in which the metal, the co-ligands, the mol. bridge, the d electron configuration, the medium, the charge, the coordination mode, or the nuclearity were modified. The new mixed-valent configurations, as obtained through various chem. approaches, display different stabilities and spectroscopic characteristics in relation to the Creutz-Taube ion; the anal. of these results serves to provide a better understanding of fundamental aspects of mol.-mediated metal-metal interaction. [on SciFinder(R)]
%0 Journal Article
%1 Kaim.2000
%A Kaim, Wolfgang
%A Klein, Axel
%A Gloeckle, Markus.
%D 2000
%J Accounts of Chemical Research
%K Creutz Taube chem ion mixed prepn review valent
%N 11
%P 755--763
%R 10.1021/ar960067k
%T Exploration of Mixed-Valence Chemistry: Inventing New Analogues of the Creutz-Taube Ion
%V 33
%X A review with 64 refs. is presented on the mixed valence chem. of analogs of the Creutz-Taube ion. Starting from the Creutz-Taube ion as the prototype of a mol.-bridged mixed-valent complex, a no. of related systems are presented in which the metal, the co-ligands, the mol. bridge, the d electron configuration, the medium, the charge, the coordination mode, or the nuclearity were modified. The new mixed-valent configurations, as obtained through various chem. approaches, display different stabilities and spectroscopic characteristics in relation to the Creutz-Taube ion; the anal. of these results serves to provide a better understanding of fundamental aspects of mol.-mediated metal-metal interaction. [on SciFinder(R)]
@article{Kaim.2000,
abstract = {A review with 64 refs. is presented on the mixed valence chem. of analogs of the Creutz-Taube ion. Starting from the Creutz-Taube ion as the prototype of a mol.-bridged mixed-valent complex, a no. of related systems are presented in which the metal, the co-ligands, the mol. bridge, the d electron configuration, the medium, the charge, the coordination mode, or the nuclearity were modified. The new mixed-valent configurations, as obtained through various chem. approaches, display different stabilities and spectroscopic characteristics in relation to the Creutz-Taube ion; the anal. of these results serves to provide a better understanding of fundamental aspects of mol.-mediated metal-metal interaction. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang and Klein, Axel and Gloeckle, Markus.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/24a2abeb4426dbed1604ebe7339ae0478/huebleriac},
doi = {10.1021/ar960067k},
interhash = {2b948d5fd223ca0759f6b5711773ff18},
intrahash = {4a2abeb4426dbed1604ebe7339ae0478},
issn = {0001-4842},
journal = {Accounts of Chemical Research},
keywords = {Creutz Taube chem ion mixed prepn review valent},
number = 11,
pages = {755--763},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Exploration of Mixed-Valence Chemistry: Inventing New Analogues of the Creutz-Taube Ion},
volume = 33,
year = 2000
}
