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Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analog of the Creutz-Taube ion

, , , and . Journal of the Chemical Society, Chemical Communications, (1993)
DOI: 10.1039/C39930001868

Abstract

Trans,mer-(P(CHMe2)3)2(CO)3Mo(m-pz)Mo(CO)3(P(CHMe2)3)2+ (pz = pyrazine), the closest yet reported organometallic analog of the Creutz-Taube ion (NH3)5Ru(m-pz)Ru(NH3)55+, was prepd. and characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochem., EPR, electronic and vibrational absorption spectroscopy. on SciFinder(R)

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