Trans,mer-(P(CHMe2)3)2(CO)3Mo(m-pz)Mo(CO)3(P(CHMe2)3)2+ (pz = pyrazine), the closest yet reported organometallic analog of the Creutz-Taube ion (NH3)5Ru(m-pz)Ru(NH3)55+, was prepd. and characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochem., EPR, electronic and vibrational absorption spectroscopy. on SciFinder(R)
%0 Journal Article
%1 Bruns.1993c
%A Bruns, Wolfgang
%A Kaim, Wolfgang
%A Waldhoer, Eberhard
%A Krejcik, Michael.
%D 1993
%J Journal of the Chemical Society, Chemical Communications
%K carbonyl dinuclear dinuclear;molybdenum electrochem molybdenum oxidn prepn pyrazine spectroelectrochem
%N 24
%P 1868--1869
%R 10.1039/C39930001868
%T Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analog of the Creutz-Taube ion
%X Trans,mer-(P(CHMe2)3)2(CO)3Mo(m-pz)Mo(CO)3(P(CHMe2)3)2+ (pz = pyrazine), the closest yet reported organometallic analog of the Creutz-Taube ion (NH3)5Ru(m-pz)Ru(NH3)55+, was prepd. and characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochem., EPR, electronic and vibrational absorption spectroscopy. on SciFinder(R)
@article{Bruns.1993c,
abstract = {Trans,mer-[(P(CHMe2)3)2(CO)3Mo(\textgreek{m}-pz)Mo(CO)3(P(CHMe2)3)2]+ (pz = pyrazine), the closest yet reported organometallic analog of the Creutz-Taube ion [(NH3)5Ru(\textgreek{m}-pz)Ru(NH3)5]5+, was prepd. and characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochem., EPR, electronic and vibrational absorption spectroscopy. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Bruns, Wolfgang and Kaim, Wolfgang and Waldhoer, Eberhard and Krejcik, Michael.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/20f50d445e09a0b5ebff1cf95b187397e/huebleriac},
doi = {10.1039/C39930001868},
interhash = {b3a6c3e86b6a89deee8d31e46a902b82},
intrahash = {0f50d445e09a0b5ebff1cf95b187397e},
issn = {0022-4936},
journal = {Journal of the Chemical Society, Chemical Communications},
keywords = {carbonyl dinuclear dinuclear;molybdenum electrochem molybdenum oxidn prepn pyrazine spectroelectrochem},
number = 24,
pages = {1868--1869},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analog of the Creutz-Taube ion},
year = 1993
}