%0 Journal Article %1 Bruns.1993c %A Bruns, Wolfgang %A Kaim, Wolfgang %A Waldhoer, Eberhard %A Krejcik, Michael. %D 1993 %J Journal of the Chemical Society, Chemical Communications %K carbonyl dinuclear dinuclear;molybdenum electrochem molybdenum oxidn prepn pyrazine spectroelectrochem %N 24 %P 1868--1869 %R 10.1039/C39930001868 %T Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analog of the Creutz-Taube ion %X Trans,mer-[(P(CHMe2)3)2(CO)3Mo(m-pz)Mo(CO)3(P(CHMe2)3)2]+ (pz = pyrazine), the closest yet reported organometallic analog of the Creutz-Taube ion [(NH3)5Ru(m-pz)Ru(NH3)5]5+, was prepd. and characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochem., EPR, electronic and vibrational absorption spectroscopy. [on SciFinder(R)]

@article{Bruns.1993c, abstract = {Trans,mer-[(P(CHMe2)3)2(CO)3Mo(\textgreek{m}-pz)Mo(CO)3(P(CHMe2)3)2]+ (pz = pyrazine), the closest yet reported organometallic analog of the Creutz-Taube ion [(NH3)5Ru(\textgreek{m}-pz)Ru(NH3)5]5+, was prepd. and characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochem., EPR, electronic and vibrational absorption spectroscopy. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Bruns, Wolfgang and Kaim, Wolfgang and Waldhoer, Eberhard and Krejcik, Michael.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/20f50d445e09a0b5ebff1cf95b187397e/huebleriac}, doi = {10.1039/C39930001868}, interhash = {b3a6c3e86b6a89deee8d31e46a902b82}, intrahash = {0f50d445e09a0b5ebff1cf95b187397e}, issn = {0022-4936}, journal = {Journal of the Chemical Society, Chemical Communications}, keywords = {carbonyl dinuclear dinuclear;molybdenum electrochem molybdenum oxidn prepn pyrazine spectroelectrochem}, number = 24, pages = {1868--1869}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analog of the Creutz-Taube ion}, year = 1993 }