Reaction of Ru(acac)2(MeCN)2, acac-=acetylacetonate, with N-phenylcamphoriminoquinone (pciq) or the new N-(2-thiomethylphenyl)-camphoriminoquinone (tciq) produces complexes Ru(acac)2(pciq) and Ru(acac)2(tciq) with N,O or N,S coordination and E or Z configuration at the C=N bond, resp. Oxidation state assignments in comparison with classical iminoquinone ligands are based on structural data in connection with DFT calculations Reversible oxidation yields complex ions RuIII(acac)2(pciq)+ and RuIII(acac)2(tciq)+ as characterized by EPR, IR and UV-vis-NIR spectroelectrochem.
%0 Journal Article
%1 Filippou.2021b
%A Filippou, Vasileios
%A Blickle, Svenja
%A Bubrin, Martina
%A Kaim, Wolfgang
%D 2021
%J Zeitschrift fuer Anorganische und Allgemeine Chemie
%K imported
%N 5
%P 525-533
%R 10.1002/zaac.202000464
%T Intramolecular Charge Transfer in Ruthenium Complexes Ru(acac)2(ciq) with Ambidentate Camphoriminoquinone (ciq) Ligands
%V 647
%X Reaction of Ru(acac)2(MeCN)2, acac-=acetylacetonate, with N-phenylcamphoriminoquinone (pciq) or the new N-(2-thiomethylphenyl)-camphoriminoquinone (tciq) produces complexes Ru(acac)2(pciq) and Ru(acac)2(tciq) with N,O or N,S coordination and E or Z configuration at the C=N bond, resp. Oxidation state assignments in comparison with classical iminoquinone ligands are based on structural data in connection with DFT calculations Reversible oxidation yields complex ions RuIII(acac)2(pciq)+ and RuIII(acac)2(tciq)+ as characterized by EPR, IR and UV-vis-NIR spectroelectrochem.
@article{Filippou.2021b,
abstract = {Reaction of [Ru(acac)2(MeCN)2], acac-=acetylacetonate, with N-phenylcamphoriminoquinone (pciq) or the new N-(2-thiomethylphenyl)-camphoriminoquinone (tciq) produces complexes [Ru(acac)2(pciq)] and [Ru(acac)2(tciq)] with N,O or N,S coordination and E or Z configuration at the C=N bond, resp. Oxidation state assignments in comparison with classical iminoquinone ligands are based on structural data in connection with DFT calculations Reversible oxidation yields complex ions [RuIII(acac)2(pciq)]+ and [RuIII(acac)2(tciq)]+ as characterized by EPR, IR and UV-vis-NIR spectroelectrochem.},
added-at = {2022-06-15T12:05:25.000+0200},
author = {Filippou, Vasileios and Blickle, Svenja and Bubrin, Martina and Kaim, Wolfgang},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/290819eaa875285c784ab85c4e79124dc/huebleriac},
doi = {10.1002/zaac.202000464},
interhash = {c6d3490af8109d03c6d42670563be279},
intrahash = {90819eaa875285c784ab85c4e79124dc},
issn = {1521-3749},
journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie},
keywords = {imported},
number = 5,
pages = {525-533},
timestamp = {2022-06-15T10:05:25.000+0200},
title = {Intramolecular Charge Transfer in Ruthenium Complexes [Ru(acac)2(ciq)] with Ambidentate Camphoriminoquinone (ciq) Ligands},
volume = 647,
year = 2021
}
