%0 Journal Article %1 vanNguyen.2010 %A van Nguyen, %A Tiritiris, Ioannis %A Winter, Rainer F. %A Sarkar, Biprajit %A Singh, Priti %A Duboc, Carole %A Munoz-Castro, Alvaro %A Arratia-Perez, Ramiro %A Kaim, Wolfgang %A Schleid, Thomas. %D 2010 %J Chemistry - A European Journal %K borate cesium cesium;dodecahydroxododecaborate closo cluster crystal cyclic dodecahydroxododecaborate electronic hydroxoborate hypocloso perhydroxylation prepn structure transition;oxidative voltammetry %N 37 %P 11242-11245, S11242/1-S11242/8 %R 10.1002/chem.201001374 %T Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12]2-/·-: Experiment and theory %V 16 %X A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2- not only to [closo-B12(OH)12]2- but also, at less-elevated temps., to the new [hypocloso-B12(OH)12]·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. [on SciFinder(R)]

@article{vanNguyen.2010, abstract = {A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2- not only to [closo-B12(OH)12]2- but also, at less-elevated temps., to the new [hypocloso-B12(OH)12]·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {{van Nguyen} and Tiritiris, Ioannis and Winter, Rainer F. and Sarkar, Biprajit and Singh, Priti and Duboc, Carole and Munoz-Castro, Alvaro and Arratia-Perez, Ramiro and Kaim, Wolfgang and Schleid, Thomas.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/291f915f66e68a5b606df645b5e6890fa/huebleriac}, doi = {10.1002/chem.201001374}, interhash = {9dc9eed84dd07fe0de9a1e1d6f3dd1e4}, intrahash = {91f915f66e68a5b606df645b5e6890fa}, issn = {0947-6539}, journal = {Chemistry - A European Journal}, keywords = {borate cesium cesium;dodecahydroxododecaborate closo cluster crystal cyclic dodecahydroxododecaborate electronic hydroxoborate hypocloso perhydroxylation prepn structure transition;oxidative voltammetry}, number = 37, pages = {11242-11245, S11242/1-S11242/8}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12]2-/·-: Experiment and theory}, volume = 16, year = 2010 }