%0 Journal Article %1 Phadnis.2002 %A Phadnis, Prasad P. %A Jain, Vimal K. %A Knodler, Axel %A Kaim, Wolfgang. %D 2002 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K arsine complex methyl palladium platinum prepn;crystal structure %N 6 %P 1332--1338 %R 10.1002/1521-3749(200206)628:6\textless1332::AID-ZAAC1332\textgreater3.0.CO;2-T %T Tripropylarsane complexes of palladium(II) and platinum(II) - syntheses, spectroscopy, and structures %V 628 %X Several Pd(II) and Pt(II) complexes of tripropylarsines (AsR3; R = Pr, iPr) [MCl2(AsR3)2], [M2Cl2(m-Cl)2(AsR3)2], [Pd2Me2(m-Cl)2(AsR3)2], [Pd2X2(m-Pz)2(AsR3)2] (X = Cl or Me, Pz = pyrazolate), [Pd2Cl2(m-Y)2(AsR3)2] (Y = OAc or SPh), [MCl(S2CNEt2)(AsR3)] and [PdCp(Cl)(AsiPr3)] (M = Pd or Pt) were prepd. All the complexes were characterized by elemental analyses, IR and 1H NMR spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The structures of [Pd2Me2(m-X)2(AsiPr3)2] (X = Cl or Pz) were established by single crystal x-ray diffraction analyses. Both of the complexes have sym-trans configuration. Strong trans influence of the Me group is reflected on the Pd-X bond distances. [on SciFinder(R)]

@article{Phadnis.2002, abstract = {Several Pd(II) and Pt(II) complexes of tripropylarsines (AsR3; R = Pr, iPr) [MCl2(AsR3)2], [M2Cl2(\textgreek{m}-Cl)2(AsR3)2], [Pd2Me2(\textgreek{m}-Cl)2(AsR3)2], [Pd2X2(\textgreek{m}-Pz)2(AsR3)2] (X = Cl or Me, Pz = pyrazolate), [Pd2Cl2(\textgreek{m}-Y)2(AsR3)2] (Y = OAc or SPh), [MCl(S2CNEt2)(AsR3)] and [PdCp(Cl)(AsiPr3)] (M = Pd or Pt) were prepd. All the complexes were characterized by elemental analyses, IR and 1H NMR spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The structures of [Pd2Me2(\textgreek{m}-X)2(AsiPr3)2] (X = Cl or Pz) were established by single crystal x-ray diffraction analyses. Both of the complexes have sym-trans configuration. Strong trans influence of the Me group is reflected on the Pd-X bond distances. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Phadnis, Prasad P. and Jain, Vimal K. and Knodler, Axel and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2e79dea4cc2fe3eaf6db38d5809f0c7d7/huebleriac}, doi = {10.1002/1521-3749(200206)628:6{\textless}1332::AID-ZAAC1332{\textgreater}3.0.CO;2-T}, interhash = {876edbdf4e7ced67fecc77eef6a82bd7}, intrahash = {e79dea4cc2fe3eaf6db38d5809f0c7d7}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {arsine complex methyl palladium platinum prepn;crystal structure}, number = 6, pages = {1332--1338}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Tripropylarsane complexes of palladium(II) and platinum(II) - syntheses, spectroscopy, and structures}, volume = 628, year = 2002 }