Tripropylarsane complexes of palladium(II) and platinum(II) - syntheses, spectroscopy, and structures

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Zeitschrift fuer Anorganische und Allgemeine Chemie, 628 (6): 1332--1338 (2002)
DOI: 10.1002/1521-3749(200206)628:6{\textless}1332::AID-ZAAC1332{\textgreater}3.0.CO;2-T


Several Pd(II) and Pt(II) complexes of tripropylarsines (AsR3; R = Pr, iPr) MCl2(AsR3)2, M2Cl2(m-Cl)2(AsR3)2, Pd2Me2(m-Cl)2(AsR3)2, Pd2X2(m-Pz)2(AsR3)2 (X = Cl or Me, Pz = pyrazolate), Pd2Cl2(m-Y)2(AsR3)2 (Y = OAc or SPh), MCl(S2CNEt2)(AsR3) and PdCp(Cl)(AsiPr3) (M = Pd or Pt) were prepd. All the complexes were characterized by elemental analyses, IR and 1H NMR spectroscopy. The stereochem. of the complexes was deduced from the spectroscopic data. The structures of Pd2Me2(m-X)2(AsiPr3)2 (X = Cl or Pz) were established by single crystal x-ray diffraction analyses. Both of the complexes have sym-trans configuration. Strong trans influence of the Me group is reflected on the Pd-X bond distances. on SciFinder(R)



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