Photoelectron-spectral data indicate that Me3SiCH2 substituents lower the 1st ionization potential of C6H6; this donor effect can be parametrized in terms of a hyperconjugation model. One-electron oxidn. in soln. of alkylsilylbenzenes (e.g., I) yield radical cations with well-resolved ESR spectra. on SciFinder(R)
%0 Journal Article
%1 Bock.1977
%A Bock, Hans
%A Kaim, Wolfgang
%A Rohwer, Hans E.
%D 1977
%J Journal of Organometallic Chemistry
%K ESR benzene benzene;silyl cation photoelectron radical silyl spectra
%N 1
%P C14-C19
%R 10.1016/S0022-328X(00)91700-5
%T Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution
%V 135
%X Photoelectron-spectral data indicate that Me3SiCH2 substituents lower the 1st ionization potential of C6H6; this donor effect can be parametrized in terms of a hyperconjugation model. One-electron oxidn. in soln. of alkylsilylbenzenes (e.g., I) yield radical cations with well-resolved ESR spectra. on SciFinder(R)
@article{Bock.1977,
abstract = {Photoelectron-spectral data indicate that Me3SiCH2 substituents lower the 1st ionization potential of C6H6; this donor effect can be parametrized in terms of a hyperconjugation model. One-electron oxidn. in soln. of alkylsilylbenzenes (e.g., I) yield radical cations with well-resolved ESR spectra. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Bock, Hans and Kaim, Wolfgang and Rohwer, Hans E.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29e3484c098fa2801644f0707b4fe70ef/b_schwederski},
doi = {10.1016/S0022-328X(00)91700-5},
interhash = {7ad5875e9d3668daaa54d01a4b5a1395},
intrahash = {9e3484c098fa2801644f0707b4fe70ef},
journal = {Journal of Organometallic Chemistry},
keywords = {ESR benzene benzene;silyl cation photoelectron radical silyl spectra},
number = 1,
pages = {C14-C19},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution},
volume = 135,
year = 1977
}