Abstract
Photoelectron-spectral data indicate that Me3SiCH2 substituents lower the 1st ionization potential of C6H6; this donor effect can be parametrized in terms of a hyperconjugation model. One-electron oxidn. in soln. of alkylsilylbenzenes (e.g., I) yield radical cations with well-resolved ESR spectra. on SciFinder(R)
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