%0 Journal Article %1 Bock.1977 %A Bock, Hans %A Kaim, Wolfgang %A Rohwer, Hans E. %D 1977 %J Journal of Organometallic Chemistry %K ESR benzene benzene;silyl cation photoelectron radical silyl spectra %N 1 %P C14-C19 %R 10.1016/S0022-328X(00)91700-5 %T Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution %V 135 %X Photoelectron-spectral data indicate that Me3SiCH2 substituents lower the 1st ionization potential of C6H6; this donor effect can be parametrized in terms of a hyperconjugation model. One-electron oxidn. in soln. of alkylsilylbenzenes (e.g., I) yield radical cations with well-resolved ESR spectra. on SciFinder(R)

@article{Bock.1977, abstract = {Photoelectron-spectral data indicate that Me3SiCH2 substituents lower the 1st ionization potential of C6H6; this donor effect can be parametrized in terms of a hyperconjugation model. One-electron oxidn. in soln. of alkylsilylbenzenes (e.g., I) yield radical cations with well-resolved ESR spectra. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Bock, Hans and Kaim, Wolfgang and Rohwer, Hans E.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29e3484c098fa2801644f0707b4fe70ef/huebleriac}, doi = {10.1016/S0022-328X(00)91700-5}, interhash = {7ad5875e9d3668daaa54d01a4b5a1395}, intrahash = {9e3484c098fa2801644f0707b4fe70ef}, journal = {Journal of Organometallic Chemistry}, keywords = {ESR benzene benzene;silyl cation photoelectron radical silyl spectra}, number = 1, pages = {C14-C19}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution}, volume = 135, year = 1977 }