The role of metal coordination in the stabilization of various oxidn. states of NOx (x = +, 0, -, 2-) and in its relation to N2O and NO2 is discussed by example of transition metal complexes. In addn. to structural information from expts. and calcns., the results of spectroscopic studies (IR, EPR) in connection with electrochem. provide evidence for the appropriate oxidn. state description and the assocd. reactivity, revealing a continuum for the charge parameter x. on SciFinder(R)
%0 Journal Article
%1 Kaim.2015
%A Kaim, Wolfgang.
%D 2015
%J Advances in Inorganic Chemistry
%K electron nitrogen oxide transfer
%P 295--313
%R 10.1016/bs.adioch.2014.10.007
%T Complete and partial electron transfer involving coordinated NOx
%V 67
%X The role of metal coordination in the stabilization of various oxidn. states of NOx (x = +, 0, -, 2-) and in its relation to N2O and NO2 is discussed by example of transition metal complexes. In addn. to structural information from expts. and calcns., the results of spectroscopic studies (IR, EPR) in connection with electrochem. provide evidence for the appropriate oxidn. state description and the assocd. reactivity, revealing a continuum for the charge parameter x. on SciFinder(R)
@article{Kaim.2015,
abstract = {The role of metal coordination in the stabilization of various oxidn. states of NOx (x = +, 0, -, 2-) and in its relation to N2O and NO2 is discussed by example of transition metal complexes. In addn. to structural information from expts. and calcns., the results of spectroscopic studies (IR, EPR) in connection with electrochem. provide evidence for the appropriate oxidn. state description and the assocd. reactivity, revealing a continuum for the charge parameter x. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2fb6cb38a2afa13886d6a5a9bb7864d53/b_schwederski},
doi = {10.1016/bs.adioch.2014.10.007},
interhash = {33649f9da81bc0117fa2e39eb0daecf9},
intrahash = {fb6cb38a2afa13886d6a5a9bb7864d53},
issn = {0898-8838},
journal = {Advances in Inorganic Chemistry},
keywords = {electron nitrogen oxide transfer},
pages = {295--313},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Complete and partial electron transfer involving coordinated NOx},
volume = 67,
year = 2015
}