Reaction of 1,4-bis(trimethylsilyl)-1,3-butadiyne with AlR3 (R = Me, Et) and K in THF has led to observation of the first examples of persistent radical di-ate complexes I, which have been characterized by ESR spectroscopy. on SciFinder(R)
Bitte melden Sie sich an um selbst Rezensionen oder Kommentare zu erstellen.
Zitieren Sie diese Publikation
Mehr Zitationsstile
- bitte auswählen -
%0 Journal Article
%1 Kaim.1988c
%A Kaim, Wolfgang.
%D 1988
%J Journal of Organometallic Chemistry
%K alkylaluminum;ESR aluminum anion;silylbutadiyne complex double organosilicon potassium potassium;ate radical reaction trialkyl trialkylaluminum trimethylsilylbutadiyne unsatd
%N 3
%P 253--257
%R 10.1016/S0022-328X(00)99386-0
%T Trapping of the coordinatively unsaturated organosilicon anion radical Me3SiC$\equiv$CC$\equiv$CSiMe3·- by double ate-complex formation with AlR3
%V 339
%X Reaction of 1,4-bis(trimethylsilyl)-1,3-butadiyne with AlR3 (R = Me, Et) and K in THF has led to observation of the first examples of persistent radical di-ate complexes I, which have been characterized by ESR spectroscopy. on SciFinder(R)
@article{Kaim.1988c,
abstract = {Reaction of 1,4-bis(trimethylsilyl)-1,3-butadiyne with AlR3 (R = Me, Et) and K in THF has led to observation of the first examples of persistent radical di-ate complexes I, which have been characterized by ESR spectroscopy. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2f02ea5e33b9d145808d9d021e281328b/huebleriac},
doi = {10.1016/S0022-328X(00)99386-0},
interhash = {0e93229788e9210d0766c22b2b11c801},
intrahash = {f02ea5e33b9d145808d9d021e281328b},
journal = {Journal of Organometallic Chemistry},
keywords = {alkylaluminum;ESR aluminum anion;silylbutadiyne complex double organosilicon potassium potassium;ate radical reaction trialkyl trialkylaluminum trimethylsilylbutadiyne unsatd},
number = 3,
pages = {253--257},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Trapping of the coordinatively unsaturated organosilicon anion radical Me3SiC$\equiv$CC$\equiv$CSiMe3·- by double ate-complex formation with AlR3},
volume = 339,
year = 1988
}