Publications

Axel Klein, Hans-Dieter Hausen, and Wolfgang. Kaim. protection of the axial positions of square-planar platinum(II) center of (2,2'-bipyridine)dimesitylplatinum, characterized by X-ray diffraction. Luminescence and electrochem. reversible formation of Platinum(III). Journal of Organometallic Chemistry, (440)1-2:207--217, 1992. [PUMA: bipyridine crystal dimesityl platinum platinum;Luminescence platinum;electrochem platinum;mol redox structure]

Neeladri Das, Atta M. Arif, Peter J. Stang, Monika Sieger, Biprajit Sarkar, Wolfgang Kaim, and Jan. Fiedler. Self-Assembly of Heterobimetallic Neutral Macrocycles Incorporating Ferrocene Spacer Groups: Spectroelectrochemical Analysis of the Double Two-Electron Oxidation of a Molecular Rectangle. Inorganic Chemistry, (44)16:5798--5804, 2005. [PUMA: anthracenediyl bridged complex;heterobimetallic crystal electrochem ferrocene macrocycle multinuclear neutral oxidn;phenanthrenediyl platinum platinyl prepn redox spacer spectroelectrochem structure]

Akbey Dogan, Biprajit Sarkar, Axel Klein, Falk Lissner, Thomas Schleid, Jan Fiedler, Stanislav Zalis, Vimal K. Jain, and Wolfgang. Kaim. Complex Reduction Chemistry of (abpy)PtCl2, abpy = 2,2'-Azobispyridine: Formation of Cyclic (m,h2:h1-abpy)PtCl22+ with a New Coordination Mode for abpy and a Near-Infrared Ligand-to-Ligand Intervalence Charge Transfer Absorption of the One-Electron Reduced State. Inorganic Chemistry, (43)19:5973--5980, 2004. [PUMA: azobispyridine chloro complex complex;platinum crystal dimer monomer platinum prepn redn structure]

Wolfgang Kaim, Akbey Dogan, Matthias Wanner, Axel Klein, Ioannis Tiritiris, Thomas Schleid, Derk J. Stufkens, Theo L. Snoeck, Eric J. L. McInnes, Jan Fiedler, and Stanislav. Zalis. Reduced and Excited States of (bpym)PtCl2n (bpym = 2,2'-Bipyrimidine; n = 1, 2): Experiments and DFT Calculations. Inorganic Chemistry, (41)16:4139--4148, 2002. [PUMA: bipyrimidine calcd complex complex;electronic complex;luminescence complex;mol complex;platinum crystal electrochem platinum prepn redn;Raman structure]

Shengfa Ye, Wolfgang Kaim, Mark Niemeyer, and Narayan S. Hosmane. Stereospecific Intramolecular S$\rightarrow$Pt Transmethylation from 8-(Methylthio)quinoline to Coordinated PtMe2: Formation of syn-fac-PtIVMe3(m-8-quinolinethiolato)2 with Stacked Quinoline Rings. Organometallics, (24)5:794--796, 2005. [PUMA: bridging crystal cyclodimer methylplatinum methylthioquinoline methylthioquinoline;thiolate mol planar platinum prepn reaction;sulfidodimethyl redox structure transmethylation]

Ece Bulak, Tereza Varnali, Brigitte Schwederski, Biprajit Sarkar, Ingo Hartenbach, Jan Fiedler, and Wolfgang. Kaim. 2,3-Bis(1-methylimidazol-2-yl)quinoxaline (bmiq), a new ligand with decoupled electron transfer and metal coordination sites: The very different redox behaviour of isoelectronic complexes with PtCl2 and AuCl2+. Dalton Transactions, (40)12:2757--2763, 2011. [PUMA: chloro complex complex;platinum crystal cyclic gold methylimidazolylquinoxaline platinum prepn structure voltammetry]

Wolfgang Kaim, Axel Klein, Steffen Hasenzahl, Hermann Stoll, Stanislav Zalis, and Jan. Fiedler. Reactions of New Organoplatinum(II) and -(IV) Complexes of 1,4-Diaza-1,3-butadienes with Light and Electrons. Emission vs Photochemistry and the Electronic Structures of Ground, Reduced, Oxidized, and Low-Lying Charge-Transfer Excited States. Organometallics, (17)2:237--247, 1998. [PUMA: HF MO alkyl aryl charge chelate chelate;DAB chelate;diazabutadiene chelate;oxidized diazabutadiene excited low lying organoplatinum platinum prepn prepn;electronic reaction;DFT structure transfer]

Prasad P. Phadnis, Vimal K. Jain, Axel Klein, Michael Weber, and Wolfgang. Kaim. Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures. Inorganica Chimica Acta, (346):119--128, 2003. [PUMA: NMR;cis acetato benzyldimethylarsine benzyldimethylarsine;crystal bridged chloro cis correlation dinuclear halo isomer mononuclear palladium platinum prepn pyrazolato structure trans trans;platinum]

Wolfgang Kaim, Akbey Dogan, Axel Klein, and Stanislav. Zalis. Complexes of 1,3-bis(diphenylphosphino)propane (dppp) with dichloroplatinum(II) and bis(chlorogold(I)): Intramolecular versus intermolecular AuI-AuI association of (m-dppp)(AuCl)2 in catena and cyclo forms. Zeitschrift fuer Anorganische und Allgemeine Chemie, (631)8:1355--1358, 2005. [PUMA: chloro complex complex;propanediphosphine crystal dinuclear gold mononuclear platinum prepn propanediphosphine structure]

Paul S. Braterman, Jae Inh Song, Conny Vogler, and Wolfgang. Kaim. EPR and absorption spectra of singly reduced mono- and dinuclear diorganoplatinum complexes of heterocyclic a-diimines. Inorganic Chemistry, (31)2:222--224, 1992. [PUMA: EPR complex diimine heterocyclic platinum reduced]

Sandip Dey, Vimal K. Jain, Axel Knoedler, and Wolfgang. Kaim. Synthesis and characterization of 3-dimethylaminopropyl selenolate complexes of palladium(II) and platinum(II). Inorganica Chimica Acta, (349):104--110, 2003. [PUMA: NMR;crystal aminopropylselenolate chloro dimethylaminopropylselenolate dinuclear palladium phosphine platinum prepn structure]

Sandip Dey, Liladhar B. Kumbhare, Vimal K. Jain, Thilo Schurr, Wolfgang Kaim, Axel Klein, and Ferdinand. Belaj. Structural variety and multiple isomerism in 1-(dimethylamino)propyl-2-chalcogenolate and 2-(dimethylamino)propyl-1-chalcogenolate complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures. European Journal of Inorganic Chemistry, 22:4510--4520, 2004. [PUMA: aminopropyl aminopropylchalcogenolate aminopropylselenolate;dichalcogenide aminopropylthiolate crystal decompn isomerism;platinum isomerism;thermal multiple palladium platinum platinum;palladium prepn regioisomer structure thiolation]

Cueneyt Kavakli, Brigitte Schwederski, Jan Fiedler, Dietrich Gudat, and Wolfgang. Kaim. Ligand-based Reduction in a Molecular Rectangle with Four Organoplatinum(IV) Vertices. Zeitschrift fuer Anorganische und Allgemeine Chemie, (636)1:114--120, 2010. [PUMA: ESR based bipyridine bipyrimidine complex ligand platinum prepn rectangle redn;electrochem redox]

Akbey Dogan, Cueneyt Kavakli, Monika Sieger, Mark Niemeyer, Biprajit Sarkar, and Wolfgang. Kaim. Structural and spectroscopic evidence for marginal metal-to-ligand charge transfer in complexes Pt(abpy)Me3X, abpy = 2,2'-azobispyridine, X = Cl, Br, I. Zeitschrift fuer Anorganische und Allgemeine Chemie, (634)14:2527--2531, 2008. [PUMA: ESR azobispyridine bromo complex complex;platinum crystal electrochem halotrimethyl iodo platinum prepn prepn;mol redn structure trimethyl]

Anshu Singhal, Vimal K. Jain, Axel Klein, Mark Niemeyer, and Wolfgang. Kaim. Thiolato-bridged \dqLinear\dq trinuclear platinum complexes Pt3(m-SR)4(dppm)22+. Inorganica Chimica Acta, (357)7:2134--2142, 2004. [PUMA: arylthiolate bridged crystal dinuclear linear methanediphosphine phenylphosphinomethane platinum prepn structure tolylthiolate trinuclear trinuclear;platinum]

Sandip Dey, Vimal K. Jain, Axel Knoedler, Axel Klein, Wolfgang Kaim, and Stanislav. Zalis. Structural Basis for Unusually Long Wavelength Charge Transfer Transitions in Complexes MCl(ECH2CH2NMe2)(PR3) (E = Te, Se; M = Pt, Pd): Experimental Results and TD-DFT Calculations. Inorganic Chemistry, (41)11:2864--2870, 2002. [PUMA: aminoethylchalcogenolate aminoethylselenolate aminoethyltellurolate complex complex;electrochem palladium phosphine platinum prepn;crystal redox structure]

Axel Klein, Thilo Schurr, Axel Knoedler, Dietrich Gudat, Karl-Wilhelm Klinkhammer, Vimal K. Jain, Stanislav Zalis, and Wolfgang. Kaim. Multiple Isomerism (cis/trans; syn/anti) in (dmso)2Pt(aryl)2 Complexes: A Combined Structural, Spectroscopic, and Theoretical Investigation. Organometallics, (24)17:4125--4131, 2005. [PUMA: DFT DMSO NMR NOESY aryl complex complex;diaryl complex;platinum conformer crystal dimethyl multinuclear platinum prepn spectra;mol structure sulfoxide]

Rohit Singh Chauhan, G. Kedarnath, Amey Wadawale, Alvaro Munoz-Castro, Ramiro Arratia-Perez, Vimal K. Jain, and Wolfgang. Kaim. Tellurium(0) as a Ligand: Synthesis and Characterization of 2-Pyridyltellurolates of Platinum(II) and Structures of Pt2-Te-3-(R)C5H3N2Te(PR'3) (R = H or Me). Inorganic Chemistry, (49)9:4179--4185, 2010. [PUMA: complex complex;platinum crystal phosphine platinum prepn pyridinetellurolate pyridyltellurolate structure tellurium]

Axel Klein, Thomas Scheiring, and Wolfgang. Kaim. Molecular and crystal structure of an organoplatinum(II) complex with dipyrido3,2-a:2',3'-cphenazine (dppz). Zeitschrift fuer Anorganische und Allgemeine Chemie, (625)7:1177--1180, 1999. [PUMA: dipyridophenazine mesityl mol platinum structure]

Paul S. Braterman, Jae Inh Song, Franz M. Wimmer, Smita Wimmer, Wolfgang Kaim, Axel Klein, and R. D. Peacock. Electrochemistry and spectroelectrochemistry (EPR, UV-visible-near-IR) of platinum(II) 2,2'-bipyridine and ring-metalated bipyridine complexes: PtII(L-) and PtI(L-) but not PtI(L). Inorganic Chemistry, (31)24:5084--5088, 1992. [PUMA: ESR;platinum UV bipyridine complex dimethylbipyridine elec electrochem electroredn;dimethylaminobipyridine phenathroline platinum potential;redn pyridine redox reversible spectrum;diaminoethane]