Thiolato-bridged tri- and dinuclear Pt complexes [Pt3(m-SR)4(dppm)2]2+ (1) and [Pt2(m-ER)2(dppm)2]2+ (2) (E = S or Se; R = Et or aryl; dppm = bis(diphenylphosphino)methane) were prepd. using the mononuclear precursors [Pt(ER)2(dppm)]. The complexes were characterized by NMR (1H, 13C, 31P, 195Pt), FTIR and FAB mass spectral data. The structure of [Pt3(m-SC6H4CH3-4)4(dppm)2][CF3SO3]2·6CH2Cl2 (1d), was established through x-ray crystallog., revealing a zigzag arrangement of the three coordination spheres around the Pt atoms. [on SciFinder(R)]
%0 Journal Article
%1 Singhal.2004
%A Singhal, Anshu
%A Jain, Vimal K.
%A Klein, Axel
%A Niemeyer, Mark
%A Kaim, Wolfgang.
%D 2004
%J Inorganica Chimica Acta
%K arylthiolate bridged crystal dinuclear linear methanediphosphine phenylphosphinomethane platinum prepn structure tolylthiolate trinuclear trinuclear;platinum
%N 7
%P 2134--2142
%R 10.1016/j.ica.2003.12.024
%T Thiolato-bridged \dqLinear\dq trinuclear platinum complexes [Pt3(m-SR)4(dppm)2]2+
%V 357
%X Thiolato-bridged tri- and dinuclear Pt complexes [Pt3(m-SR)4(dppm)2]2+ (1) and [Pt2(m-ER)2(dppm)2]2+ (2) (E = S or Se; R = Et or aryl; dppm = bis(diphenylphosphino)methane) were prepd. using the mononuclear precursors [Pt(ER)2(dppm)]. The complexes were characterized by NMR (1H, 13C, 31P, 195Pt), FTIR and FAB mass spectral data. The structure of [Pt3(m-SC6H4CH3-4)4(dppm)2][CF3SO3]2·6CH2Cl2 (1d), was established through x-ray crystallog., revealing a zigzag arrangement of the three coordination spheres around the Pt atoms. [on SciFinder(R)]
@article{Singhal.2004,
abstract = {Thiolato-bridged tri- and dinuclear Pt complexes [Pt3(\textgreek{m}-SR)4(dppm)2]2+ (1) and [Pt2(\textgreek{m}-ER)2(dppm)2]2+ (2) (E = S or Se; R = Et or aryl; dppm = bis(diphenylphosphino)methane) were prepd. using the mononuclear precursors [Pt(ER)2(dppm)]. The complexes were characterized by NMR (1H, 13C, 31P, 195Pt), FTIR and FAB mass spectral data. The structure of [Pt3(\textgreek{m}-SC6H4CH3-4)4(dppm)2][CF3SO3]2·6CH2Cl2 (1d), was established through x-ray crystallog., revealing a zigzag arrangement of the three coordination spheres around the Pt atoms. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Singhal, Anshu and Jain, Vimal K. and Klein, Axel and Niemeyer, Mark and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2b80ec568de1cb0962da6b4ee2b3f17c8/b_schwederski},
doi = {10.1016/j.ica.2003.12.024},
interhash = {0d112e0d1754c02eefe00722b5aeed7f},
intrahash = {b80ec568de1cb0962da6b4ee2b3f17c8},
issn = {0020-1693},
journal = {Inorganica Chimica Acta},
keywords = {arylthiolate bridged crystal dinuclear linear methanediphosphine phenylphosphinomethane platinum prepn structure tolylthiolate trinuclear trinuclear;platinum},
number = 7,
pages = {2134--2142},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Thiolato-bridged {\dq}Linear{\dq} trinuclear platinum complexes [Pt3(\textgreek{m}-SR)4(dppm)2]2+},
volume = 357,
year = 2004
}
