%0 Journal Article %1 Singhal.2004 %A Singhal, Anshu %A Jain, Vimal K. %A Klein, Axel %A Niemeyer, Mark %A Kaim, Wolfgang. %D 2004 %J Inorganica Chimica Acta %K arylthiolate bridged crystal dinuclear linear methanediphosphine phenylphosphinomethane platinum prepn structure tolylthiolate trinuclear trinuclear;platinum %N 7 %P 2134--2142 %R 10.1016/j.ica.2003.12.024 %T Thiolato-bridged \dqLinear\dq trinuclear platinum complexes [Pt3(m-SR)4(dppm)2]2+ %V 357 %X Thiolato-bridged tri- and dinuclear Pt complexes [Pt3(m-SR)4(dppm)2]2+ (1) and [Pt2(m-ER)2(dppm)2]2+ (2) (E = S or Se; R = Et or aryl; dppm = bis(diphenylphosphino)methane) were prepd. using the mononuclear precursors [Pt(ER)2(dppm)]. The complexes were characterized by NMR (1H, 13C, 31P, 195Pt), FTIR and FAB mass spectral data. The structure of [Pt3(m-SC6H4CH3-4)4(dppm)2][CF3SO3]2·6CH2Cl2 (1d), was established through x-ray crystallog., revealing a zigzag arrangement of the three coordination spheres around the Pt atoms. [on SciFinder(R)]

@article{Singhal.2004, abstract = {Thiolato-bridged tri- and dinuclear Pt complexes [Pt3(\textgreek{m}-SR)4(dppm)2]2+ (1) and [Pt2(\textgreek{m}-ER)2(dppm)2]2+ (2) (E = S or Se; R = Et or aryl; dppm = bis(diphenylphosphino)methane) were prepd. using the mononuclear precursors [Pt(ER)2(dppm)]. The complexes were characterized by NMR (1H, 13C, 31P, 195Pt), FTIR and FAB mass spectral data. The structure of [Pt3(\textgreek{m}-SC6H4CH3-4)4(dppm)2][CF3SO3]2·6CH2Cl2 (1d), was established through x-ray crystallog., revealing a zigzag arrangement of the three coordination spheres around the Pt atoms. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Singhal, Anshu and Jain, Vimal K. and Klein, Axel and Niemeyer, Mark and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2b80ec568de1cb0962da6b4ee2b3f17c8/huebleriac}, doi = {10.1016/j.ica.2003.12.024}, interhash = {0d112e0d1754c02eefe00722b5aeed7f}, intrahash = {b80ec568de1cb0962da6b4ee2b3f17c8}, issn = {0020-1693}, journal = {Inorganica Chimica Acta}, keywords = {arylthiolate bridged crystal dinuclear linear methanediphosphine phenylphosphinomethane platinum prepn structure tolylthiolate trinuclear trinuclear;platinum}, number = 7, pages = {2134--2142}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Thiolato-bridged {\dq}Linear{\dq} trinuclear platinum complexes [Pt3(\textgreek{m}-SR)4(dppm)2]2+}, volume = 357, year = 2004 }