Correlation between structure and electron transfer in organometallic model compound for flavin with \dqButterfly\dq conformation. Journal of Organometallic Chemistry, (456)2:167--173, 1993. [PUMA: conformation;silyldihydropyrazine crystal cyclic deriv;ESR deriv;flavin dihydropyrazine model mol prepn silyldihydropyrazine structure voltammetry]
Organometallic complex cations (hn-CnR'n)M(RN:CHCH:NR)Cl+ of 1,4-diazabutadienes (M = Os and n = 6 or M = Rh, Ir and n = 5, R = 2,6-dialkylphenyl). Structures and reduction to neutral compounds (hn-CnR'n)M(RNCH:CHNR). Zeitschrift fuer Anorganische und Allgemeine Chemie, (627)4:620--630, 2001. [PUMA: azabutadiene complex complex;diazabutadiene complex;redn complex;redox complex;rhodium crystal diazabutadiene diisopropylphenyl iridium mol osmium potential prepn redox redox;crystal redox;mol structure structure;iridium]
Insertion of CO2, COS and CS2 into the N-Si bond of extremely electron-rich 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine and formation of a new poly(N,S) heterocyclic system by multiple cycloaddition. Journal of Organometallic Chemistry, (501)1-2:283--292, 1995. [PUMA: bond carbon carbonyl crystal cycloaddn dioxide disulfide insertion mol nitrogen prepn pyrazine silicon silicon;sulfide silyl;diepiazanothiocinopyrazinethione structure;insertion sulfide]
Double cyclometalation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties. Journal of Organometallic Chemistry, (693)8-9:1703--1706, 2008. [PUMA: complex crystal cyclometalated dimethylsulfoxide electrochem mesityl mesityl;cyclometalation mol platinum redn structure tetrazine thienyl]
Different orbital occupation by an added single electron in 1,10-phenanthroline and its 3,4,7,8-tetramethyl derivative. Evidence from electron paramagnetic resonance spectroscopy of the anion radicals and of their dimesitylplatinum(II) complexes. X-ray molecular structure of dimesityl(1,10-phenanthroline)platinum(II). Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12:2121--2126, 1995. [PUMA: ESR anion complex crystal dimesityl mesityl mol phenanthroline platinum platinum;phenanthroline potential;radical redox structure]
A Systematic Synthetic Approach to a Novel, Mixed 2,3-C2B4- and 2,4-C2B4-Erbium(III) Carborane Bent-Sandwich Complex. Organometallics, (14)3:1101--1103, 1995. [PUMA: bent carborane crystal erbium mol prepn sandwich sandwich;erbium structure]
Reversible radical complex formation of an organometallic diplatinum(IV) compound. Journal of Organometallic Chemistry, (692)15:3151--3155, 2007. [PUMA: complex complex;ESR complex;trimethyl crystal electrochem methylpyridyl mol platinum prepn radical redn spectra structure tetrazine trimethylplatinum]
Metalloradical Compounds with 1,2-Dipivaloylhydrazido Ligands: Electron Transfer and Alkylation/Protonation Effects. European Journal of Inorganic Chemistry, (2019)21:2639--2647, 2019. [PUMA: alkylation calcn complex complex;spectroelectrochem crystal dipivaloylhydrazido effect mol osmium prepn protonation ruthenium structure structure;electron transfer]
Asymmetrical Diruthenium Complex Bridged by a Redox-Active Ligand. Inorganic Chemistry, (51)3:1675--1684, 2012. [PUMA: asym azobis calcn cationic complex complex;mol cymene mol prepn pyridine ruthenium structure structure;crystal]
Modelling bis-(1-methylimidazol-2-yl)glyoxal, 'big', in complex ions M(big)2+n, M = Au, Pt, Cu, Re, Zn: A DFT study. Molecular Physics, (104)5-7:833--838, 2006. [PUMA: back bonding complex glyoxal metal methylimidazol mol structure]
(Acetato)tris(N,N'-diphenylacetamidinato)dimolybdenum and bis(acetato)bisN,N'-bis(2,6-xylyl)acetamidinatodimolybdenum tetrakis(tetrahydrofuranate). Two new mixed-ligand quadruply bonded dimolybdenum compounds. Inorganic Chemistry, (20)3:930--934, 1981. [PUMA: acetato mol molybdenum phenylacetamidinato;xylylacetamidinato structure]
Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E = B-In). Angewandte Chemie, International Edition, (40)3:566--568, 2001. [PUMA: alkyl cluster crystal gallium mol nonanuclear prepn structure]
First structural characterization of an easily oxidized derivative of 1,4-dihydroquinoxaline. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (48)6:713--718, 1993. [PUMA: butyldimethylsilyl butyldimethylsilylquinoxaline;electrochem butyldimethylsilylquinoxaline;mol butyldimethylsilylquinoxaline;quinoxaline crystal mol oxidn structure]
Gas-Phase Structure of the Monomeric Alkylgallium(I) Compound GaC(SiMe3)3 and the Electrochemical Behavior of Ga4C(SiMe3)34 and In4C(SiMe3)34 with EPR Evidence for a Ga4R4 Radical Anion. Organometallics, (15)4:1146--1150, 1996. [PUMA: ESR anion cyclic diffraction formation gallium indium;electron mol monomeric radical silylmethyl silylmethylgallium;silylmethyl structure voltammetry]
Electron-rich olefins. 1. The relationship between structure, spectroscopy, and reactivity of tetrakis(trimethylsilylmethyl)ethene. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (43)1:82--88, 1988. [PUMA: crystal mol structure structure;mol tetrakistrimethylsilylmethyl tetrakistrimethylsilylmethylethene;ethene tetrakistrimethylsilylmethylethene;silylmethylethene]
Organometallic platinum(ii) complexes of methyl-substituted phenanthrolines. Journal of the Chemical Society, Dalton Transactions, 11:2371--2378, 2002. [PUMA: absorption complex complex;electrochem complex;mesityl crystal mesityl methyl methylphenanthroline mol phenyl platinum prepn redox spectra structure]
Electronic and molecular structure of 2,2'-bipyrimidine-bridged bis(organoplatinum) complexes in various oxidation states. Radical-bridged diplatinum species and the absence of a Pt(III)/Pt(II) mixed-valent intermediate. Inorganica Chimica Acta, (264)1-2:269--278, 1997. [PUMA: bipyrimidine bridged crystal dinuclear;electrochem dinuclear;electronic diplatinum;DFT mol organoplatinum oxidn platinum structure]
Dimethylplatinum(II) and tetramethylplatinum(IV) complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazoles: Experimental and DFT-calculated structures and NMR spectra. Journal of Organometallic Chemistry, (655)1-2:218--226, 2002. [PUMA: NMR;crystal alkylthiomethyl benzimidazole chelate chelate;mol fluxionality methyl mol optimized platinum prepn prepn;DFT proton structure]
Dinuclear and trinuclear organometallic complexes (ReS4)MCl(C5Me5), M = Rh, Ir, and (m-WS4)IrCl(C5Me5)2. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (56)9:940--946, 2001. [PUMA: charge crystal cyclopentadienyl dinuclear interaction iridium mol potential prepn redn rhodium structure structure;tetrathiotungstate tetrathiorhenate;electrochem tetrathiorhenate;tetrathiorhenate tetrathiotungstate transfer]
An Oxide Ion Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the \dqCarbons Apart\dq C2B4-Carborane Ligands. Organometallics, (22)22:4390--4392, 2003. [PUMA: THF cluster complex;oxide crystal dicarbahexaborate encapsulating holmacarborane holmium ion mol prepn reaction sodium structure trichloride]