Publications

Axel Knoedler, Matthias Wanner, Wolfgang Kaim, and Jan. Fiedler. Organometallic 5d6 transition metal complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazole ligands: Structures and electrochemical oxidation. Zeitschrift fuer Anorganische und Allgemeine Chemie, (628)5:1132--1139, 2002. [PUMA: alkylthiomethyl benzimidazole complex complex;mol electrochem osmium oxidn;crystal prepn rhenium structure]

Steffen Hasenzahl, Hans-Dieter Hausen, and Wolfgang. Kaim. A tale of two complexes, PtMen(RN=CHCH=NR) (n = 2 and n = 4, R = cyclohexyl): Why do PtII and PtIV complexes exhibit virtually identical redox behavior and colors?. Chemistry - A European Journal, (1)1:95--99, 1995. [PUMA: charge complex complex;EPR complex;MO complex;crystal complex;electrochem complex;mol complex;platinum diazabutadiene methyl platinum prepn property structure transfer]

Amit Das, Thomas Michael Scherer, Abhishek Dutta Chowdhury, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar. Lahiri. Asymmetrical Diruthenium Complex Bridged by a Redox-Active Ligand. Inorganic Chemistry, (51)3:1675--1684, 2012. [PUMA: asym azobis calcn cationic complex complex;mol cymene mol prepn pyridine ruthenium structure structure;crystal]

F. Baumann, E. Dormann, Y. Ehleiter, W. Kaim, J. Karcher, M. Kelemen, R. Krammer, D. Saurenz, D. Stalke, C. Wachter, G. Wolmershauser, and H. Sitzmann. Structure and reactivity of paramagnetic cyclopentadienyl cobalt complexes with bulky alkyl substituents. Journal of Organometallic Chemistry, (587)2:267--283, 1999. [PUMA: bulky carbonyl cobalt complex complex;mol complex;nitrosyl cyclopentadienyl prepn reaction;crystal structure structure;cobalt]

Subrata Kundu, Soumen Sinhababu, Sayan Dutta, Totan Mondal, Debasis Koley, Birger Dittrich, Brigitte Schwederski, Wolfgang Kaim, A. Claudia Stueckl, and Herbert W. Roesky. Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals. Chemical Communications (Cambridge, United Kingdom), (53)76:10516--10519, 2017. [PUMA: ESR alkylaminocarbene aluminum bivalent complex complex;mol complex;optimized cyclic geometry prepn spectra;crystal structure tetracoordinate]

Joerg Maurer, Michael Linseis, Biprajit Sarkar, Brigitte Schwederski, Mark Niemeyer, Wolfgang Kaim, Stanislav Zalis, Chris Anson, Manfred Zabel, and Rainer F. Winter. Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: A case of non-innocence in organometallic chemistry. Journal of the American Chemical Society, (130)1:259--268, 2008. [PUMA: ESR carbonyl complex complex;crystal complex;mol complex;ruthenium conjugated conjugation effect electrooxidn;spectroelectrochem hexenyl oxidn phosphine pi potential prepn pyrenylethenyl pyridine ruthenium spectra structure styryl vinyl vinylruthenium]

Sascha Berger, Thomas Scheiring, Jan Fiedler, and Wolfgang. Kaim. Coupling of organometallic reaction centers through the non-planar bridging ligand 2,3-bis(2-pyridyl)pyrazine. Zeitschrift fuer Anorganische und Allgemeine Chemie, (630)13-14:2409--2417, 2004. [PUMA: binuclear bis complex complex;mol complex;redox complex;rhodium crystal half iridium mononuclear pentamethylcyclopentadienyl potential prepn pyridylpyrazine rhodium sandwich structure]

Ece Bulak, Tereza Varnali, Brigitte Schwederski, Denis Bubrin, Jan Fiedler, and Wolfgang. Kaim. Separation of Metal Binding and Electron Transfer Sites as a Strategy To Stabilize the Ligand-Reduced and Metal-Oxidized Form of Mo(CO)4L. Organometallics, (30)23:6441--6445, 2011. [PUMA: DFT;seven EPR chelate complex;mol complex;optimized crystal electrochem geometry membered metallacycle methylimidazolylquinoxaline molybdenum prepn seven structure]

Narayan S. Hosmane, Temesgen Demissie, Hongming Zhang, John A. Maguire, William N. Lipscomb, Frank Baumann, and Wolfgang. Kaim. Synthesis and Crystal Structure of the First Polymeric Cesium Compound of a Carborane Ligand System. Organometallics, (17)3:293--295, 1998. [PUMA: carborane cesium complex complex;mol prepn structure structure;crystal]

Sayak Roy, Biprajit Sarkar, Denis Bubrin, Mark Niemeyer, Stanislav Zalis, Goutam Kumar Lahiri, and Wolfgang. Kaim. Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through p/p interaction in an isolated complex. Journal of the American Chemical Society, (130)46:15230--15231, 2008. [PUMA: complex complex;mol copper diphenylphosphinoferrocene monovalent ortho phenanthrenequinone prepn quinone structure structure;crystal]

Rajkumar Jana, Svenja Blickle, Falk Lissner, Ingo Hartenbach, Martina Bubrin, Brigitte Schwederski, and Wolfgang. Kaim. Organometal coordination by purines: Semi-chelate bonding of modified guanine and isocaffeine with bis(diorganylphosphino)ferrocene-copper. Journal of Organometallic Chemistry, (782):62--68, 2015. [PUMA: complex complex;mol complex;organophosphinoferrocene copper crystal organophosphinoferrocene prepn purine structure]

Thomas Scheiring, Jan Fiedler, and Wolfgang. Kaim. Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex (h5-C5Me5)ClRh(m-bptz)Re(CO)3Cl(PF6), bptz = 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Organometallics, (20)7:1437--1441, 2001. [PUMA: carbonyl complex complex;cyclic complex;electrochem complex;mol complex;rhenium crystal cyclopentadienyl electrochem;spectroelectrochem heterodinuclear prepn pyridyltetrazine redn rhenium rhodium structure voltammetry]

Wolfgang Kaim, Akbey Dogan, Matthias Wanner, Axel Klein, Ioannis Tiritiris, Thomas Schleid, Derk J. Stufkens, Theo L. Snoeck, Eric J. L. McInnes, Jan Fiedler, and Stanislav. Zalis. Reduced and Excited States of (bpym)PtCl2n (bpym = 2,2'-Bipyrimidine; n = 1, 2): Experiments and DFT Calculations. Inorganic Chemistry, (41)16:4139--4148, 2002. [PUMA: bipyrimidine calcd complex complex;electronic complex;luminescence complex;mol complex;platinum crystal electrochem platinum prepn redn;Raman structure]

Subrata Kundu, Prinson P. Samuel, Soumen Sinhababu, Anna V. Luebben, Birger Dittrich, Diego M. Andrada, Gernot Frenking, A. Claudia Stueckl, Brigitte Schwederski, Alexa Paretzki, Wolfgang Kaim, and Herbert W. Roesky. Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors. Journal of the American Chemical Society, (139)32:11028--11031, 2017. [PUMA: cAAC complex;mol complex;silyl crystal dimer diradical disilane prepn pyrrolidinylidene radical stabilized structure]

Dongren Wang, Joerg Unold, Martina Bubrin, Iris Elser, Wolfgang Frey, Wolfgang Kaim, Guangjuan Xu, and Michael R. Buchmeiser. Ruthenium-triazene complexes as latent catalysts for UV-induced ROMP. European Journal of Inorganic Chemistry, (2013)31:5462--5468, 2013. [PUMA: carbene carbene;ruthenium catalyst complex complex;mol complex;polymn crystal metathesis opening photocatalyst photochem prepn ring ruthenium structure triazene]

Michael Linseis, Rainer F. Winter, Biprajit Sarkar, Wolfgang Kaim, and Stanislav. Zalis. Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin. Organometallics, (27)14:3321--3324, 2008. [PUMA: calcn centered complex complex;mol complex;styryl delocalization electron ethene ligand olefin oxidn phosphine prepn ruthenium structure styryl tetradonor tetranuclear]

Soumen Sinhababu, Subrata Kundu, Mujahuddin M. Siddiqui, Alexander N. Paesch, Regine Herbst-Irmer, Brigitte Schwederski, Pinaki Saha, Lili Zhao, Gernot Frenking, Wolfgang Kaim, Dietmar Stalke, and Herbert W. Roesky. Synthesis of cAAC stabilized biradical of \textquotedblMe2Si\textquotedbl and \textquotedblMe2SiCl\textquotedbl monoradical from Me2SiCl2 - an important feedstock material. Chemical Communications (Cambridge, United Kingdom), (55)31:4534--4537, 2019. [PUMA: alkylaminocarbene biradical cAAC complex complex;EPR complex;mol complex;silylene crystal cyclic prepn radical silylene spectra stabilized structure]

Soumen Sinhababu, Subrata Kundu, Mujahuddin M. Siddiqui, Alexander N. Paesch, Regine Herbst-Irmer, Brigitte Schwederski, Pinaki Saha, Lili Zhao, Gernot Frenking, Wolfgang Kaim, Dietmar Stalke, and Herbert W. Roesky. Synthesis of cAAC stabilized biradical of \textquotedblMe2Si\textquotedbl and \textquotedblMe2SiCl\textquotedbl monoradical from Me2SiCl2 - an important feedstock material. Chemical Communications (Cambridge, United Kingdom), (55)31:4534--4537, 2019. [PUMA: alkylaminocarbene biradical cAAC complex complex;EPR complex;mol complex;silylene crystal cyclic prepn radical silylene spectra stabilized structure]

Michael Linseis, Rainer F. Winter, Biprajit Sarkar, Wolfgang Kaim, and Stanislav. Zalis. Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin. Organometallics, (27)14:3321--3324, 2008. [PUMA: calcn centered complex complex;mol complex;styryl delocalization electron ethene ligand olefin oxidn phosphine prepn ruthenium structure styryl tetradonor tetranuclear]

Dongren Wang, Joerg Unold, Martina Bubrin, Iris Elser, Wolfgang Frey, Wolfgang Kaim, Guangjuan Xu, and Michael R. Buchmeiser. Ruthenium-triazene complexes as latent catalysts for UV-induced ROMP. European Journal of Inorganic Chemistry, (2013)31:5462--5468, 2013. [PUMA: carbene carbene;ruthenium catalyst complex complex;mol complex;polymn crystal metathesis opening photocatalyst photochem prepn ring ruthenium structure triazene]