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Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin

, , , , and . Organometallics, 27 (14): 3321--3324 (2008)
DOI: 10.1021/om8003338

Abstract

The tetrakis(4-styryl)ethene (TSTE4-)-bridged tetraruthenium complex (PiPr3)2(CO)ClRu4μ4-(CH:CHC6H4)4(C:C) undergoes four consecutive oxidns. at low potential. The ligand-dominated nature of these processes is confirmed by spectroscopic and quantum-chem. investigations. on SciFinder(R)

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