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Coordination alternatives in dinuclear bis(pyridin-2-ylalkyl)benzylamine copper(II) complexes with OH-, RO-, F-, or Cl- bridges: Experimental structures and DFT preferences

J. Manzur, A. Vega, A. Garcia, C. Acuna, M. Sieger, B. Sarkar, M. Niemeyer, F. Lissner, T. Schleid, and W. Kaim. European Journal of Inorganic Chemistry, (2007)
DOI: 10.1002/ejic.200700637

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Univ. -Prof. Dr. rer. nat. Biprajit Sarkar University of Stuttgart

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Fluorinated click-derived tripodal ligands drive spin crossover in both iron(ii) and cobalt(ii) complexesM. Nößler, D. Hunger, N. Neuman, M. Reimann, F. Reichert, M. Winkler, J. Klein, T. Bens, L. Suntrup, S. Demeshko and 4 other author(s). Dalton transactions, 51 (27): 10507-10517 (2022)Forty Years after the Discovery of Its Nucleolytic Activity : [Cu(phen)2]2+ Shows Unattended DNA Cleavage Activity upon FluorinationC. Lüdtke, S. Sobottka, J. Heinrich, P. Liebing, S. Wedepohl, B. Sarkar, and N. Kulak. Chemistry - a European journal, 27 (10): 3273-3277 (2020)Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear (μ4-TCNX)[Ru(NH3)5]48+, TCNX = TCNE and TCNQ, from DFT calculationsS. Zalis, B. Sarkar, C. Duboc, and W. Kaim. Monatshefte fuer Chemie, 140 (7): 765--773 (2009)N2.3-: Filling a Gap in the N2n- SeriesW. Kaim, and B. Sarkar. Angewandte Chemie, International Edition, 48 (50): 9409--9411 (2009)The Metal-NO Interaction in the Redox Systems [Cl5Os(NO)]n-, n = 1-3, and cis-[(bpy)2ClOs(NO)]2+/+: Calculations, Structural, Electrochemical, and Spectroscopic ResultsP. Singh, B. Sarkar, M. Sieger, M. Niemeyer, J. Fiedler, S. Zalis, and W. Kaim. Inorganic Chemistry, 45 (12): 4602--4609 (2006)Organoosmium complexes of imidazole-containing chelate acceptor ligandsO. Sarper, B. Sarkar, J. Fiedler, F. Lissner, and W. Kaim. Inorganica Chimica Acta, 363 (12): 3070--3077 (2010)Long-range electronic coupling in various oxidation states of a C4-linked tris(b-diketonato)ruthenium dimerY. Hoshino, S. Higuchi, J. Fiedler, C. Su, A. Knodler, B. Schwederski, B. Sarkar, H. Hartmann, and W. Kaim. Angewandte Chemie, International Edition, 42 (6): 674--677 (2003)Valence structures of the diastereomeric complexes meso- and rac-[Ru2(acac)4(m-Q)]n (n = 2-, 1-, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexaneD. Kumbhakar, B. Sarkar, A. Das, A. Das, S. Mobin, J. Fiedler, W. Kaim, and G. Lahiri. Dalton Transactions, (2009)Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(m-tppz)Ru(L)Cl]+, L = b-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazineT. Kundu, D. Schweinfurth, B. Sarkar, T. Mondal, J. Fiedler, S. Mobin, V. Puranik, W. Kaim, and G. Lahiri. Dalton Transactions, 41 (43): 13429--13440 (2012)Mixed valency in ruthenium complexes - Coordinative aspectsW. Kaim, and B. Sarkar. Coordination Chemistry Reviews, 251 (3+4): 584--594 (2007)

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Univ. -Prof. Dr. rer. nat. Biprajit Sarkar University of Stuttgart

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