%0 Journal Article %1 Knodler.2002 %A Knodler, Axel %A Kaim, Wolfgang %A Jain, Vimal K. %A Zalis, Stanislav. %D 2002 %J Journal of Organometallic Chemistry %K NMR;crystal alkylthiomethyl benzimidazole chelate chelate;mol fluxionality methyl mol optimized platinum prepn prepn;DFT proton structure %N 1-2 %P 218--226 %R 10.1016/S0022-328X(02)01564-4 %T Dimethylplatinum(II) and tetramethylplatinum(IV) complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazoles: Experimental and DFT-calculated structures and NMR spectra %V 655 %X (L)PtMen where [n = 2, 4; L = mmb = [1-methyl-(2-methylthiomethyl)-1H-benzimidazole], mtb = [1-methyl-(2-tert-butylthiomethyl)-1H-benzimidazole]] were characterized by x-ray crystallog. [except for (mmb)PtMe2] and by 1H and 195Pt NMR spectroscopy. The tetramethylplatinum(IV) complexes exhibit a variable degree of dynamic 1H NMR behavior due to the mobility at the thioether S atom in the nonplanar five-membered chelate ring, as supported by structural anal. D.-functional theory (DFT) calcns. were used to reproduce the structural features and the 1H NMR chem. shifts. In comparison with other late transition metal complexes of these N-S chelate ligands the Me4Pt and esp. the Me2Pt compds. exhibit a relatively stronger preference of the metal for the S donor. [on SciFinder(R)]

@article{Knodler.2002, abstract = {(L)PtMen where [n = 2, 4; L = mmb = [1-methyl-(2-methylthiomethyl)-1H-benzimidazole], mtb = [1-methyl-(2-tert-butylthiomethyl)-1H-benzimidazole]] were characterized by x-ray crystallog. [except for (mmb)PtMe2] and by 1H and 195Pt NMR spectroscopy. The tetramethylplatinum(IV) complexes exhibit a variable degree of dynamic 1H NMR behavior due to the mobility at the thioether S atom in the nonplanar five-membered chelate ring, as supported by structural anal. D.-functional theory (DFT) calcns. were used to reproduce the structural features and the 1H NMR chem. shifts. In comparison with other late transition metal complexes of these N-S chelate ligands the Me4Pt and esp. the Me2Pt compds. exhibit a relatively stronger preference of the metal for the S donor. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Knodler, Axel and Kaim, Wolfgang and Jain, Vimal K. and Zalis, Stanislav.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2ec7efaa82274be84cf2fbf9f7c1025ea/huebleriac}, doi = {10.1016/S0022-328X(02)01564-4}, interhash = {b799683a904c272023c1d468b6a2a91c}, intrahash = {ec7efaa82274be84cf2fbf9f7c1025ea}, journal = {Journal of Organometallic Chemistry}, keywords = {NMR;crystal alkylthiomethyl benzimidazole chelate chelate;mol fluxionality methyl mol optimized platinum prepn prepn;DFT proton structure}, number = {1-2}, pages = {218--226}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Dimethylplatinum(II) and tetramethylplatinum(IV) complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazoles: Experimental and DFT-calculated structures and NMR spectra}, volume = 655, year = 2002 }