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Data for: Olefin Metathesis under Spatial Confinement and Continuous Flow: Investigation of Isomeric Side Reactions with a Grubbs-Hoveyda Type Catalyst

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Dataset, (2024)Related to: A. Böth, T. Roider, F. Ziegler, X. Xie, M. R. Buchmeiser, U. Tallarek, Olefin Metathesis under Spatial Confinement and Continuous Flow: Investigation of Isomeric Side Reactions with a Grubbs-Hoveyda Type Catalyst, ChemCatChem 2023, 15, e202201268. doi: 10.1002/cctc.202201268.
DOI: 10.18419/darus-3784

Abstract

Olefin Metathesis under Spatial Confinement and Continuous Flow: We study olefin metathesis with a focus on isomers formed as by-products. For that purpose, a 2D-LC/MS system is implemented, showing decisive advantages over common 1H NMR analysis. As a consequence, it became possible to determine the influence of catalyst deactivation on both yield and selectivity of the reaction.

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