Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands
C. Bessenbacher, and W. Kaim. Zeitschrift fuer Anorganische und Allgemeine Chemie, (1989)
Abstract
Re(CO)3ClL (L = pyrazine-2-dimethylcarboxamide, 1-ethylpyrazinium-3-dimethylcarboxamide, 1,3-dimethyllumazine, 2,5-diacetylpyrazine, lumiflavine and riboflavin were prepd. and studied by cyclic voltammetry and spectroscopy (IR, electronic, ESR). s-Polarization and p-back-bonding by the organometallic fragment cause stabilization of the reduced (radical) form and of the first metal-to-ligand charge transfer excited state. on SciFinder(R)
%0 Journal Article
%1 Bessenbacher.1989d
%A Bessenbacher, Christian
%A Kaim, Wolfgang.
%D 1989
%J Zeitschrift fuer Anorganische und Allgemeine Chemie
%K acetylpyrazine carbonyl carbonylpyrazine complex complex;cyclic complex;lumazine complex;lumiflavine complex;pyrazinecarboxamide complex;riboflavin rhenium voltammetry
%P 39--52
%T Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands
%V 577
%X Re(CO)3ClL (L = pyrazine-2-dimethylcarboxamide, 1-ethylpyrazinium-3-dimethylcarboxamide, 1,3-dimethyllumazine, 2,5-diacetylpyrazine, lumiflavine and riboflavin were prepd. and studied by cyclic voltammetry and spectroscopy (IR, electronic, ESR). s-Polarization and p-back-bonding by the organometallic fragment cause stabilization of the reduced (radical) form and of the first metal-to-ligand charge transfer excited state. on SciFinder(R)
@article{Bessenbacher.1989d,
abstract = {Re(CO)3ClL (L = pyrazine-2-dimethylcarboxamide, 1-ethylpyrazinium-3-dimethylcarboxamide, 1,3-dimethyllumazine, 2,5-diacetylpyrazine, lumiflavine and riboflavin were prepd. and studied by cyclic voltammetry and spectroscopy (IR, electronic, ESR). \textgreek{s}-Polarization and \textgreek{p}-back-bonding by the organometallic fragment cause stabilization of the reduced (radical) form and of the first metal-to-ligand charge transfer excited state. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Bessenbacher, Christian and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2c21363501353bcb3b0a561b5fbe797de/b_schwederski},
interhash = {c7cfcf5f81a4d8adc2620fc7568f217b},
intrahash = {c21363501353bcb3b0a561b5fbe797de},
issn = {0044-2313},
journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie},
keywords = {acetylpyrazine carbonyl carbonylpyrazine complex complex;cyclic complex;lumazine complex;lumiflavine complex;pyrazinecarboxamide complex;riboflavin rhenium voltammetry},
pages = {39--52},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Stabilization of biochemical relevant intermediates by metal coordination. IV. Rhenium(I) complexes of flavin- and pterin-analogous nitrogen-oxygen chelate ligands},
volume = 577,
year = 1989
}