A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster closo-B12H122- not only to closo-B12(OH)122- but also, at less-elevated temps., to the new hypocloso-B12(OH)12·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. on SciFinder(R)
%0 Journal Article
%1 vanNguyen.2010
%A van Nguyen,
%A Tiritiris, Ioannis
%A Winter, Rainer F.
%A Sarkar, Biprajit
%A Singh, Priti
%A Duboc, Carole
%A Munoz-Castro, Alvaro
%A Arratia-Perez, Ramiro
%A Kaim, Wolfgang
%A Schleid, Thomas.
%D 2010
%J Chemistry - A European Journal
%K borate cesium cesium;dodecahydroxododecaborate closo cluster crystal cyclic dodecahydroxododecaborate electronic hydroxoborate hypocloso perhydroxylation prepn structure transition;oxidative voltammetry
%N 37
%P 11242-11245, S11242/1-S11242/8
%R 10.1002/chem.201001374
%T Oxidative perhydroxylation of closo-B12H122- to the stable inorganic cluster redox system B12(OH)122-/·-: Experiment and theory
%V 16
%X A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster closo-B12H122- not only to closo-B12(OH)122- but also, at less-elevated temps., to the new hypocloso-B12(OH)12·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. on SciFinder(R)
@article{vanNguyen.2010,
abstract = {A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2- not only to [closo-B12(OH)12]2- but also, at less-elevated temps., to the new [hypocloso-B12(OH)12]·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {{van Nguyen} and Tiritiris, Ioannis and Winter, Rainer F. and Sarkar, Biprajit and Singh, Priti and Duboc, Carole and Munoz-Castro, Alvaro and Arratia-Perez, Ramiro and Kaim, Wolfgang and Schleid, Thomas.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/291f915f66e68a5b606df645b5e6890fa/huebleriac},
doi = {10.1002/chem.201001374},
interhash = {9dc9eed84dd07fe0de9a1e1d6f3dd1e4},
intrahash = {91f915f66e68a5b606df645b5e6890fa},
issn = {0947-6539},
journal = {Chemistry - A European Journal},
keywords = {borate cesium cesium;dodecahydroxododecaborate closo cluster crystal cyclic dodecahydroxododecaborate electronic hydroxoborate hypocloso perhydroxylation prepn structure transition;oxidative voltammetry},
number = 37,
pages = {11242-11245, S11242/1-S11242/8},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12]2-/·-: Experiment and theory},
volume = 16,
year = 2010
}
