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Oxidative perhydroxylation of closo-B12H122- to the stable inorganic cluster redox system B12(OH)122-/·-: Experiment and theory

, , , , , , , , , und . Chemistry - A European Journal 16 (37): 11242-11245, S11242/1-S11242/8 (2010)

Zusammenfassung

A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster closo-B12H122- not only to closo-B12(OH)122- but also, at less-elevated temps., to the new hypocloso-B12(OH)12·- radical anion. Both approx. icosahedral closo and hypocloso cluster ions were structurally characterized as the Cs salts and their properties were assessed exptl. and theor. on SciFinder(R)

Links und Ressourcen

DOI:
10.1002/chem.201001374
BibTeX-Schlüssel:
vanNguyen.2010
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