%0 Generic %1 panyam2022rhiiiinheterocyclic %A Panyam, Pradeep Kumar Reddy %A Atwi, Boshra %A Ziegler, Felix %A Frey, Wolfgang %A Nowakowski, Michal %A Bauer, Matthias %A Buchmeiser, Michael %D 2022 %K %R 10.18419/darus-2473 %T Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes %X Novel Rh(III) pentamethylcyclopentadienyl and Rh(I) complexes containing chelating N-heterocyclic carbenes have been prepared and used in the hydrosilylation of 1-alkynes. Selected catalysts were immobilized within the mesopores of SBA-15. The confinement effects either provided by the ligands or the mesoporous support have been studied and allow for hydrosilylation with β(Z)-selectivity of up to 100 % with both Rh(I) and Rh(III) complexes. All primary data files of measurements and processed data of the journal article mentioned under related publications from Buchmeiser group can be found here. The following dataset contains the following data types: NMR Spectra and HRMS data. The Crystal data (see related datasets) is deposited in the Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC).

@misc{panyam2022rhiiiinheterocyclic, abstract = {Novel Rh(III) pentamethylcyclopentadienyl and Rh(I) complexes containing chelating N-heterocyclic carbenes have been prepared and used in the hydrosilylation of 1-alkynes. Selected catalysts were immobilized within the mesopores of SBA-15. The confinement effects either provided by the ligands or the mesoporous support have been studied and allow for hydrosilylation with β(Z)-selectivity of up to 100 % with both Rh(I) and Rh(III) complexes. All primary data files of measurements and processed data of the journal article mentioned under related publications from Buchmeiser group can be found here. The following dataset contains the following data types: NMR Spectra and HRMS data. The Crystal data (see related datasets) is deposited in the Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC).}, added-at = {2023-08-31T15:01:35.000+0200}, affiliation = {Panyam, Pradeep Kumar Reddy/University of Stuttgart, Atwi, Boshra/University of Stuttgart, Ziegler, Felix/University of Stuttgart, Frey, Wolfgang/University of Stuttgart, Nowakowski, Michal/, Bauer, Matthias/University of Paderborn, Buchmeiser, Michael/University of Stuttgart}, author = {Panyam, Pradeep Kumar Reddy and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michal and Bauer, Matthias and Buchmeiser, Michael}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2562b6a978e7ba8d1e9c33b2629f85e02/puma-wartung}, doi = {10.18419/darus-2473}, howpublished = {Dataset}, interhash = {21d7126615e005eaf9297ccb009b4036}, intrahash = {562b6a978e7ba8d1e9c33b2629f85e02}, keywords = {}, note = {Related to: Felix Ziegler, Johannes Teske, Iris Elser, Michael Dyballa, Wolfgang Frey, Hamzeh Kraus, Niels Hansen, Julia Rybka, Ulrich Tallarek, and Michael R. Buchmeiser. Journal of the American Chemical Society 2019 141 (48), 19014-19022. doi: 10.1021/jacs.9b08776}, orcid-numbers = {Panyam, Pradeep Kumar Reddy/0000-0001-6315-2747, Ziegler, Felix/0000-0002-2785-8133, Frey, Wolfgang/0000-0002-6522-4190, Bauer, Matthias/0000-0002-9294-6076, Buchmeiser, Michael/0000-0001-6472-5156}, timestamp = {2023-08-31T13:01:35.000+0200}, title = {Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes}, year = 2022 }