Persistent cation radicals containing carboxamide and thiophosphinic amide functions. The one electron oxidation of acceptor stabilized 1,4-dihydropyrazines
An electrochem. study showed that the 1,4-dihydropyrazine system (I; R = H) is sufficiently p electron rich to accommodate the p accepting N-substituents in I R = Ac, P(S)Me2, without losing its propensity to undergo one electron oxidn. to give the corresponding persistent radical cations. These radicals were characterized by ESR spectroscopy. on SciFinder(R)
%0 Journal Article
%1 Bessenbacher.1985
%A Bessenbacher, Christian
%A Gross, Renate
%A Kaim, Wolfgang.
%D 1985
%J Journal of the Chemical Society, Chemical Communications
%K acetylpyrazine bisdimethylphosphinothioylpyrazine cation;methylphosphinothioylpyrazine diacetyl diacetylpyrazine dimethylphosphinothioyl electrochem oxidn oxidn;ESR oxidn;pyrazine radical
%N 20
%P 1369--1370
%R 10.1039/c39850001369
%T Persistent cation radicals containing carboxamide and thiophosphinic amide functions. The one electron oxidation of acceptor stabilized 1,4-dihydropyrazines
%X An electrochem. study showed that the 1,4-dihydropyrazine system (I; R = H) is sufficiently p electron rich to accommodate the p accepting N-substituents in I R = Ac, P(S)Me2, without losing its propensity to undergo one electron oxidn. to give the corresponding persistent radical cations. These radicals were characterized by ESR spectroscopy. on SciFinder(R)
@article{Bessenbacher.1985,
abstract = {An electrochem. study showed that the 1,4-dihydropyrazine system (I; R = H) is sufficiently \textgreek{p} electron rich to accommodate the \textgreek{p} accepting N-substituents in I [R = Ac, P(S)Me2], without losing its propensity to undergo one electron oxidn. to give the corresponding persistent radical cations. These radicals were characterized by ESR spectroscopy. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Bessenbacher, Christian and Gross, Renate and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21a7c41b9ea24e986cdb51df56c58efcd/b_schwederski},
doi = {10.1039/c39850001369},
interhash = {e0944f2d0935d93e18a4894684359953},
intrahash = {1a7c41b9ea24e986cdb51df56c58efcd},
issn = {0022-4936},
journal = {Journal of the Chemical Society, Chemical Communications},
keywords = {acetylpyrazine bisdimethylphosphinothioylpyrazine cation;methylphosphinothioylpyrazine diacetyl diacetylpyrazine dimethylphosphinothioyl electrochem oxidn oxidn;ESR oxidn;pyrazine radical},
number = 20,
pages = {1369--1370},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Persistent cation radicals containing carboxamide and thiophosphinic amide functions. The one electron oxidation of acceptor stabilized 1,4-dihydropyrazines},
year = 1985
}
