Heterocyclic radical anions as ligands: An unexpected coordination change in pentacarbonylmetal complexes
W. Kaim, and V. Kasack. Angewandte Chemie, 94 (9):
712--713(1982)
Abstract
M(CO)6 (M = Cr, W, Mo) react in THF with the radical anion I to give (CO)5M2L-. (M = Cr, Mo; L = I; X = O, S, Se; M = W; X = O, S) and (CO)5WL-. (X = Se). In (CO)5WL-., L is coordinated to W through the Se atom. The complexes were detected by ESR spectra. on SciFinder(R)
%0 Journal Article
%1 Kaim.1982c
%A Kaim, Wolfgang
%A Kasack, Volker.
%D 1982
%J Angewandte Chemie
%K ESR VIB benzo benzochalcogenadiazole;oxadiazole carbonyl carbonyl;selenadiazole carbonyl;sulfadiazole group
%N 9
%P 712--713
%T Heterocyclic radical anions as ligands: An unexpected coordination change in pentacarbonylmetal complexes
%V 94
%X M(CO)6 (M = Cr, W, Mo) react in THF with the radical anion I to give (CO)5M2L-. (M = Cr, Mo; L = I; X = O, S, Se; M = W; X = O, S) and (CO)5WL-. (X = Se). In (CO)5WL-., L is coordinated to W through the Se atom. The complexes were detected by ESR spectra. on SciFinder(R)
@article{Kaim.1982c,
abstract = {M(CO)6 (M = Cr, W, Mo) react in THF with the radical anion I to give {[(CO)5M]2L}-. (M = Cr, Mo; L = I; X = O, S, Se; M = W; X = O, S) and {(CO)5WL}-. (X = Se). In {[(CO)5W]L}-., L is coordinated to W through the Se atom. The complexes were detected by ESR spectra. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Kaim, Wolfgang and Kasack, Volker.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/210481207494b1ba280cd180c99a8061c/b_schwederski},
interhash = {a128bb71df3a8eb5a649f9460f9bc689},
intrahash = {10481207494b1ba280cd180c99a8061c},
issn = {0044-8249},
journal = {Angewandte Chemie},
keywords = {ESR VIB benzo benzochalcogenadiazole;oxadiazole carbonyl carbonyl;selenadiazole carbonyl;sulfadiazole group},
number = 9,
pages = {712--713},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Heterocyclic radical anions as ligands: An unexpected coordination change in pentacarbonylmetal complexes},
volume = 94,
year = 1982
}