%0 Journal Article %1 Kaim.1982c %A Kaim, Wolfgang %A Kasack, Volker. %D 1982 %J Angewandte Chemie %K ESR VIB benzo benzochalcogenadiazole;oxadiazole carbonyl carbonyl;selenadiazole carbonyl;sulfadiazole group %N 9 %P 712--713 %T Heterocyclic radical anions as ligands: An unexpected coordination change in pentacarbonylmetal complexes %V 94 %X M(CO)6 (M = Cr, W, Mo) react in THF with the radical anion I to give [(CO)5M]2L-. (M = Cr, Mo; L = I; X = O, S, Se; M = W; X = O, S) and (CO)5WL-. (X = Se). In [(CO)5W]L-., L is coordinated to W through the Se atom. The complexes were detected by ESR spectra. [on SciFinder(R)]

@article{Kaim.1982c, abstract = {M(CO)6 (M = Cr, W, Mo) react in THF with the radical anion I to give {[(CO)5M]2L}-. (M = Cr, Mo; L = I; X = O, S, Se; M = W; X = O, S) and {(CO)5WL}-. (X = Se). In {[(CO)5W]L}-., L is coordinated to W through the Se atom. The complexes were detected by ESR spectra. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Kasack, Volker.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/210481207494b1ba280cd180c99a8061c/huebleriac}, interhash = {a128bb71df3a8eb5a649f9460f9bc689}, intrahash = {10481207494b1ba280cd180c99a8061c}, issn = {0044-8249}, journal = {Angewandte Chemie}, keywords = {ESR VIB benzo benzochalcogenadiazole;oxadiazole carbonyl carbonyl;selenadiazole carbonyl;sulfadiazole group}, number = 9, pages = {712--713}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Heterocyclic radical anions as ligands: An unexpected coordination change in pentacarbonylmetal complexes}, volume = 94, year = 1982 }