Publications

Andreas F. Stange, Torsten Sixt, and Wolfgang. Kaim. Highly dissymmetric chelate coordination of 3,4,7,8-tetramethyl-1,10-phenanthroline to CuI(SR). Chemical Communications (Cambridge, United Kingdom), 4:469--470, 1998. [PUMA: 1 phenanthroline thiolate complex complex;structure copper structure;crystal prepn structure]

Monika Sieger, Conny Vogler, Axel Klein, Axel Knoedler, Matthias Wanner, Jan Fiedler, Stanislav Zalis, Theo L. Snoeck, and Wolfgang. Kaim. Geometrical and Electronic Structures of Dinuclear Complex Ions (μ-bpym)Cu(EAr3)222+ with Intramolecular \dqOrganic Sandwich\dq Formation (E = P or As; Ar = Aryl; bpym = 2,2'-Bipyrimidine). Inorganic Chemistry, (44)13:4637--4643, 2005. [PUMA: dinuclear complex copper redn complex;electrochem complex;luminescence phosphine bipyrimidine structure;crystal arsine prepn structure]

Cheng-Yong Su, Yue-Peng Cai, Chun-Long Chen, Mark D. Smith, Wolfgang Kaim, and Hans-Conrad. Zur Loye. Ligand-Directed Molecular Architectures: Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms. Journal of the American Chemical Society, (125)28:8595--8613, 2003. [PUMA: structure;silver complex benzimidazolylmethylbenzene metal metallacycle structure;transition structure transition polynuclear copper complex;nickel structure;crystal prepn prism]

Rajkumar Jana, Falk Lissner, and Wolfgang. Kaim. Coordinative Saturation of the Pterin Heterocycle by Ferrocenylcopper(I) Complex Fragments. Zeitschrift fuer Anorganische und Allgemeine Chemie, (641)2:261--265, 2015. [PUMA: complex diphosphinoferrocene pivaloylpterin copper hexanuclear structure;crystal prepn structure]

Sayak Roy, Biprajit Sarkar, Denis Bubrin, Mark Niemeyer, Stanislav Zalis, Goutam Kumar Lahiri, and Wolfgang. Kaim. Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through p/p interaction in an isolated complex. Journal of the American Chemical Society, (130)46:15230--15231, 2008. [PUMA: diphenylphosphinoferrocene ortho monovalent complex copper complex;mol phenanthrenequinone structure;crystal quinone prepn structure]

Markus Albrecht, Klaus Hubler, Thomas Scheiring, and Wolfgang. Kaim. Copper(I) and copper(II) complexes of the bidentate imidazole/thioether ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole. Inorganica Chimica Acta, (287)2:204--208, 1999. [PUMA: complex copper structure;crystal thiomethylbenzimidazole prepn structure]

Natasa Doslik, Torsten Sixt, and Wolfgang. Kaim. The first structural characterization of an azoaromatic radical anion stabilized by dicopper(I) coordination. Angewandte Chemie, International Edition, (37)17:2403--2404, 1998. [PUMA: dinuclear azochloropyrimidine triphenylphosphine dinuclear;redn copper phenylphosphine potential structure;crystal prepn structure]

Andreas F. Stange, Karl Wilhelm Klinkhammer, and Wolfgang. Kaim. A Tetragonal Bisphenoidal Tetracopper(I) Arrangement Supported by a Potentially Tridentate Ligand Containing Thiolate, Secondary Amine, and 2-Pyridine Functions: Hydrogen-Bonded Instead of Cu(I)-Coordinated Pyridine Rings in an S4-Symmetric Compound. Inorganic Chemistry, (35)13:4087--4089, 1996. [PUMA: tetranuclear complex copper structure;crystal mercaptoethylpicolylamine prepn structure]

A. Knodler, K. Hubler, T. Sixt, and W. Kaim. A copper(I) dimer Cu(L)(CH3CN)2(BF4)2 with the new chelating and bridging tridentate ligand 1-(2-pyridylmethyl)-2-(2-pyridyl)benzimidazole (L). Inorganic Chemistry Communications, (3)4:182--184, 2000. [PUMA: pyridylmethyl redn dinuclear;electrochem structure dinuclear benzimidazole copper pyridyl acetonitrile structure;copper oxidn pyridylmethylpyridylbenzimidazole structure;crystal prepn]

Manuela Schwach, Hans-Dieter Hausen, and Wolfgang. Kaim. The First Crystal Structure of a Metal-Stabilized Tetrazine Anion Radical: Formation of a Dicopper Complex through Self-Assembly in a Comproportionation Reaction. Inorganic Chemistry, (38)10:2242--2243, 1999. [PUMA: dinuclear pyridyltetrazine copper phosphine structure;crystal prepn structure]

Andreas F. Stange, Axel Klein, Karl-Wilhelm Klinkhammer, and Wolfgang. Kaim. Aggregation control of copper(I) thiolates through substituent size and ancillary chelate ligands: Closely related mono-, di-, tri- and tetranuclear complexes. Inorganica Chimica Acta, (324)1,2:336--341, 2001. [PUMA: phenanthroline thiolate blue complex copper model complex;protein structure;crystal prepn structure]

Shengfa Ye, Wolfgang Kaim, Biprajit Sarkar, Brigitte Schwederski, Falk Lissner, Thomas Schleid, Carole Duboc-Toia, and Jan. Fiedler. First crystal structure determination and high-frequency EPR study of an organoarsanecopper radical complex. Inorganic Chemistry Communications, (6)9:1196--1200, 2003. [PUMA: pyridyltetrazine complex copper complex;ESR complex;electrochem redox structure;crystal arsine prepn structure]

Cheng-Yong Su, Sen Liao, Matthias Wanner, Jan Fiedler, Cheng Zhang, Bei-Sheng Kang, and Wolfgang. Kaim. The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands. Dalton Transactions, 2:189--202, 2003. [PUMA: quinolylsulfanyldioxaoctane complex copper redn complex;electrochem sulfanylquinoline quinolinylsulfanylmethylbenzene structure;crystal quinolylsulfanyloxapentane prepn structure]

Wolfgang Kaim, Christoph Titze, Thilo Schurr, Monika Sieger, Max Lawson, Jeanne Jordanov, Dario Rojas, Ana M. Garcia, and Jorge. Manzur. Reactivity of copper(I) complexes with tripodal ligands towards O2: Structures of a precursor L3CuI(NCCH3)(BF4), L3 = tris(3-isopropyl-4,5-trimethylenepyrazolyl)methane and of its oxidation product L3CuII(m-OH)2CuIIL3(BF4)2 with strong antiferromagnetic spin-spin coupling. Zeitschrift fuer Anorganische und Allgemeine Chemie, (631)13-14:2568--2574, 2005. [PUMA: dinuclear;magnetic complex hydroxy structure coupling dinuclear copper trimethylenepyrazolyl property acetonitrile complex;copper structure;crystal mononuclear methane antiferromagnetic prepn]

Jochen Rall, Andreas F. Stange, Klaus Hubler, and Wolfgang. Kaim. A coordination-induced 1,4 $\rightarrow$ 1,2-quinonediimine isomerization. Angewandte Chemie, International Edition, (37)19:2681--2682, 1998. [PUMA: azophenine complex copper complex;isomerization complexation structure;crystal prepn structure]

Markus Gloeckle, Klaus Huebler, Hans-Juergen Kuemmerer, Gert Denninger, and Wolfgang. Kaim. Dicopper(I) Complexes with Reduced States of 3,6-Bis(2'-pyrimidyl)-1,2,4,5-tetrazine: Crystal Structures and Spectroscopic Properties of the Free Ligand, a Radical Species, and a Complex of the 1,4-Dihydro Form. Inorganic Chemistry, (40)10:2263--2269, 2001. [PUMA: dinuclear pyrimidyltetrazine complex copper complex;ESR structure;crystal prepn structure]