Publications

Ralph Huebner, Biprajit Sarkar, Jan Fiedler, Stanislav Zalis, and Wolfgang. Kaim. Metal(IV) Complexes M(LN,O,S)2n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2- with Coordinating Thioether Appendix. European Journal of Inorganic Chemistry, (2012)22:3569-3576, S3569/1-S3569/5, 2012. [PUMA: calcn complex complex;DFT complex;ESR complex;mononuclear crystal cyclic mononuclear osmium prepn ruthenium spectra structure;UV thiophenylamidophenolate tridentate voltammetry]

Fridmann M. Hornung, Frank Baumann, Wolfgang Kaim, Jose A. Olabe, Leonardo D. Slep, and Jan. Fiedler. Spectroelectrochemical Characterization of the Two-Step Redox System (μ-pz)Os(CN)52n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System. Inorganic Chemistry, (37)2:311--316, 1998. [PUMA: charge cyano dinuclear dinuclear;electrochem dinuclear;osmium osmium oxidn prepn pyrazine spectra spectroelectrochem transfer]

Torsten Sixt, Wolfgang Kaim, and Wilhelm. Preetz. Characterization of the inorganic/organometallic osmium(IV) compound Cp*2OsIVCl2OsIVCl6 as formed by the reaction of OsCl3 with pentamethylcyclopentadiene in air. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (55)3/4:235--237, 2000. [PUMA: chloroosmate chloroosmate;pentamethylcyclopentadiene complexation crystal osmium pentamethylcyclopentadienyl prepn;mol structure trichloride]

Shengfa Ye, Biprajit Sarkar, Carole Duboc, Jan Fiedler, and Wolfgang. Kaim. The Redox Series M(bpy)2(Q)n+, M = Ru or Os, Q = 3,5-Di-tert-butyl-N-phenyl-1,2-benzoquinonemonoimine. Isolation and a Complete X and W Band EPR Study of the Semiquinone States (n = 1). Inorganic Chemistry, (44)8:2843--2847, 2005. [PUMA: EPR benzoquinonemonoimine osmium potential potential;ruthenium prepn redox spectroelectrochem]

Markus Glockle, Wolfgang Kaim, and Jan. Fiedler. Stepwise and chemically reversible reduction of (μ-bmtz)MCl(η6-cym)2PF62 (M = Ru, Os; bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons. Zeitschrift fuer Anorganische und Allgemeine Chemie, (627)7:1441--1453, 2001. [PUMA: ESR cymene;ruthenium dinuclear electrochem osmium pyrimidyltetrazine redn redn;spectroelectrochem ruthenium]