Stepwise and chemically reversible reduction of (μ-bmtz)MCl(η6-cym)2PF62 (M = Ru, Os; bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons
M. Glockle, W. Kaim, and J. Fiedler. Zeitschrift fuer Anorganische und Allgemeine Chemie, 627 (7):
1441--1453(2001)
Abstract
The title compds. were synthesized and characterized spectroscopically. Anal. of cyclic voltammetry in conjunction with spectroelectrochem. (UV/visible/NIR, ESR) allowed the authors to identify the products of sequential, chem. reversible redn. with up to six electrons. It is the first time that the mol. coupling of electron transfer steps (E) and bond breaking/bond forming chem. processes (C) was studied for a diruthenium system. In that case, the chem. reversible sequence E, EC, EEC, E and E was obsd. whereas the diosmium analog showed the unusual sequence E, EC, E, EEC and E. on SciFinder(R)
%0 Journal Article
%1 Glockle.2001
%A Glockle, Markus
%A Kaim, Wolfgang
%A Fiedler, Jan.
%D 2001
%J Zeitschrift fuer Anorganische und Allgemeine Chemie
%K ESR cymene;ruthenium dinuclear electrochem osmium pyrimidyltetrazine redn redn;spectroelectrochem ruthenium
%N 7
%P 1441--1453
%T Stepwise and chemically reversible reduction of (μ-bmtz)MCl(η6-cym)2PF62 (M = Ru, Os; bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons
%V 627
%X The title compds. were synthesized and characterized spectroscopically. Anal. of cyclic voltammetry in conjunction with spectroelectrochem. (UV/visible/NIR, ESR) allowed the authors to identify the products of sequential, chem. reversible redn. with up to six electrons. It is the first time that the mol. coupling of electron transfer steps (E) and bond breaking/bond forming chem. processes (C) was studied for a diruthenium system. In that case, the chem. reversible sequence E, EC, EEC, E and E was obsd. whereas the diosmium analog showed the unusual sequence E, EC, E, EEC and E. on SciFinder(R)
@article{Glockle.2001,
abstract = {The title compds. were synthesized and characterized spectroscopically. Anal. of cyclic voltammetry in conjunction with spectroelectrochem. (UV/visible/NIR, ESR) allowed the authors to identify the products of sequential, chem. reversible redn. with up to six electrons. It is the first time that the mol. coupling of electron transfer steps (E) and bond breaking/bond forming chem. processes (C) was studied for a diruthenium system. In that case, the chem. reversible sequence E, EC, EEC, E and E was obsd. whereas the diosmium analog showed the unusual sequence E, EC, E, EEC and E. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Glockle, Markus and Kaim, Wolfgang and Fiedler, Jan.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/23da6415137a0b59d8ccdba43b2c4e02c/b_schwederski},
interhash = {618f95dd74d3fbc580fd6ffadacfad23},
intrahash = {3da6415137a0b59d8ccdba43b2c4e02c},
issn = {0044-2313},
journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie},
keywords = {ESR cymene;ruthenium dinuclear electrochem osmium pyrimidyltetrazine redn redn;spectroelectrochem ruthenium},
number = 7,
pages = {1441--1453},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Stepwise and chemically reversible reduction of {(μ-bmtz)[MCl(η6-cym)]2}[PF6]2 (M = Ru, Os; bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons},
volume = 627,
year = 2001
}
