Publications

Steffen Hasenzahl, Wolfgang Kaim, and Thomas. Stahl. Charge and electron transfer from metal-to-carbon bonds of Main Group organometallics MRn (M = Al, Ga, Zn) to aromatic N-heterocycles: Colored precursor compounds and radical complex formation. Inorganica Chimica Acta, (225)1-2:23--34, 1994. [PUMA: Group aluminum bond carbon charge gallium metal organometallic organometallic;Main organometallic;heterocycle reaction transfer zinc]

Werner Uhl, Thomas Spies, Detlev Haase, Rainer Winter, and Wolfgang. Kaim. Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands. Organometallics, (19)6:1128--1131, 2000. [PUMA: bond bridging ferrocenedicarboxylate ferrocenedicarboxylate;gallium ferrocenedicarboxylate;oxidn gallium macrocycle macrocycle;crystal potential prepn structure structure;mol]

Thomas Pott, Peter Jutzi, Wolfgang Kaim, Wolfgang W. Schoeller, Beate Neumann, Anja Stammler, Hans-Georg Stammler, and Matthias. Wanner. Reactivity of \dqGaI\dq Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions. Organometallics, (21)15:3169--3172, 2002. [PUMA: B3LYP ESR calcn diazabutadiene diazabutadiene;heterocycle formation gallium heterocycle;crystal heterocycle;gallium in iodide mol monoanion paramagnetic prepn reaction situ spectra structure]

Werner Uhl, Lars Cuypers, Wolfgang Kaim, Brigitte Schwederski, and Rainer. Koch. Ga9(CMe3)9.bul.--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium. Angewandte Chemie, International Edition, (42)21:2422--2423, 2003. [PUMA: alkyl anion butyl cluster crystal gallium mol prepn radical structure structure;tertiary]

Dimple P. Dutta, Vimal K. Jain, Axel Knoedler, and Wolfgang. Kaim. Dithiocarbamates of gallium(III) and indium(III): Syntheses, spectroscopy, and structures. Polyhedron, (21)2:239--246, 2002. [PUMA: complex complex;dithiocarbamate crystal dithiocarbamate gallium indium prepn structure]

Arne Haaland, Kjell-Gunnar Martinsen, H. V. Volden, Wolfgang Kaim, Eberhard Waldhoer, Werner Uhl, and Uwe. Schuetz. Gas-Phase Structure of the Monomeric Alkylgallium(I) Compound GaC(SiMe3)3 and the Electrochemical Behavior of Ga4C(SiMe3)34 and In4C(SiMe3)34 with EPR Evidence for a Ga4R4 Radical Anion. Organometallics, (15)4:1146--1150, 1996. [PUMA: ESR anion cyclic diffraction formation gallium indium;electron mol monomeric radical silylmethyl silylmethylgallium;silylmethyl structure voltammetry]

Werner Uhl, Lars Cuypers, Klaus Harms, Wolfgang Kaim, Matthias Wanner, Rainer Winter, Rainer Koch, and Wolfgang. Saak. Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E = B-In). Angewandte Chemie, International Edition, (40)3:566--568, 2001. [PUMA: alkyl cluster crystal gallium mol nonanuclear prepn structure]

Nils Wiberg, Kerstin Amelunxen, Heinrich Noth, Holger Schwenk, Wolfgang Kaim, Axel Klein, and Thomas. Scheiring. Compounds of silicon. 113. Sterically overloaded supersilyl compounds. 12. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: A new type of compound for a heavy Group 13 element. Angewandte Chemie, International Edition in English, (36)11:1213--1215, 1997. [PUMA: aluminum butylsilyl dinuclear gallium prepn prepn;crystal radical radical;ESR radical;gallium structure structure;silyl structure;supersilyl supersilyl]

Wolfgang Kaim, and Walter. Matheis. Bis(1,4-di-tert-butyl-1,4-diazabutadiene)gallium is not a gallium(II) compound. Journal of the Chemical Society, Chemical Communications, 8:597--598, 1991. [PUMA: ESR complex complex;gallium complex;hyperfine complex;valence coupling ditertbutyldiazabutadiene ditertibutyldiazabutadiene gallium valence]