Several complexes MS2CNR3 (1) (M = Ga or In; R = CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2), MCl2S2CN(CH2CH2)2O (2) (M = Ga or In), MClS2CN(CH2CH2)2O2 (3) (M = Ga or In), GaS2CN(CH2CH2)2OS2P(OR)22 (4) (R = Et, Pri) and MS2CNR(SCH2CH2)2O (5) (M = Ga or In; R=CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2) were prepd. All the complexes were characterized by elemental anal., IR and NMR (1H, 13C1H) spectroscopy. 71Ga NMR chem. shifts and half line widths are influenced by the coordination no. of Ga and the substituents on the ligand moiety. Single crystal x-ray structures of two complexes MS2CN(CH2CH2)2O3 (M = Ga, In) were detd. on SciFinder(R)
%0 Journal Article
%1 Dutta.2002
%A Dutta, Dimple P.
%A Jain, Vimal K.
%A Knoedler, Axel
%A Kaim, Wolfgang.
%D 2002
%J Polyhedron
%K complex complex;dithiocarbamate crystal dithiocarbamate gallium indium prepn structure
%N 2
%P 239--246
%R 10.1016/S0277-5387(01)00990-1
%T Dithiocarbamates of gallium(III) and indium(III): Syntheses, spectroscopy, and structures
%V 21
%X Several complexes MS2CNR3 (1) (M = Ga or In; R = CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2), MCl2S2CN(CH2CH2)2O (2) (M = Ga or In), MClS2CN(CH2CH2)2O2 (3) (M = Ga or In), GaS2CN(CH2CH2)2OS2P(OR)22 (4) (R = Et, Pri) and MS2CNR(SCH2CH2)2O (5) (M = Ga or In; R=CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2) were prepd. All the complexes were characterized by elemental anal., IR and NMR (1H, 13C1H) spectroscopy. 71Ga NMR chem. shifts and half line widths are influenced by the coordination no. of Ga and the substituents on the ligand moiety. Single crystal x-ray structures of two complexes MS2CN(CH2CH2)2O3 (M = Ga, In) were detd. on SciFinder(R)
@article{Dutta.2002,
abstract = {Several complexes [M{S2CNR}3] (1) (M = Ga or In; R = CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2), [MCl2{S2CN(CH2CH2)2O}] (2) (M = Ga or In), [MCl{S2CN(CH2CH2)2O}2] (3) (M = Ga or In), [Ga{S2CN(CH2CH2)2O}{S2P(OR)2}2] (4) (R = Et, Pri) and [M{S2CNR}{(SCH2CH2)2O}] (5) (M = Ga or In; R=CH2CH2OCH2CH2, CH2CH2N(Me)CH2CH2) were prepd. All the complexes were characterized by elemental anal., IR and NMR (1H, 13C{1H}) spectroscopy. 71Ga NMR chem. shifts and half line widths are influenced by the coordination no. of Ga and the substituents on the ligand moiety. Single crystal x-ray structures of two complexes [M{S2CN(CH2CH2)2O}3] (M = Ga, In) were detd. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Dutta, Dimple P. and Jain, Vimal K. and Knoedler, Axel and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/212f4e55480feb0366edcd3eb25c6d028/b_schwederski},
doi = {10.1016/S0277-5387(01)00990-1},
interhash = {cd602951f7b52f3a6d2a8b237e2e050c},
intrahash = {12f4e55480feb0366edcd3eb25c6d028},
issn = {0277-5387},
journal = {Polyhedron},
keywords = {complex complex;dithiocarbamate crystal dithiocarbamate gallium indium prepn structure},
number = 2,
pages = {239--246},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Dithiocarbamates of gallium(III) and indium(III): Syntheses, spectroscopy, and structures},
volume = 21,
year = 2002
}
