Publications

Hans Bock, Wolfgang Kaim, A. Semkow, and Heinrich. Noeth. Chemistry of boron. 97. Radical ions. 17. Structure changes during the oxidation of boron-, carbon-, silicon-, or phosphorus-substituted hydrazines. Angewandte Chemie, (90)4:308--310, 1978. [PUMA: boron hydrazine ion;silicon radical review review;phosphorus review;review review;structure substituted]

Mixed-valence intermediates as ideal targets for spectroelectrochemistry (SEC): Spectroelectrochem. In Wolfgang Kaim, Biprajit Sarkar, and Goutam Kumar. Lahiri (Eds.), Royal Society of Chemistry, 2008. [PUMA: ESR IR catalysis electrocatalysis intermediate mixed optical redox review;review spectroelectrochem valence vibrational]

W. Kaim. Complexes with 2,2'-azobis(pyridine) and related 'S-frame' bridging ligands containing the azo function. Coordination Chemistry Reviews, (219-221):463--488, 2001. [PUMA: azobispyridine charge complex complex;structure intermediate metal review review;isomerism review;mixed review;oxidn review;radical review;review state transfer valence]

Wolfgang. Kaim. The transition metal coordination chemistry of anion radicals. Coordination Chemistry Reviews, (76):187--235, 1987. [PUMA: anion carbon contg prepn property;spectra radical review review;complex review;nitrogen review;oxygen review;phosphorus review;review review;structure review;sulfur]

Wolfgang Kaim, and Jochen. Rall. Copper - A \dqmodern\dq bioelement. Angewandte Chemie, International Edition in English, (35)1:43--60, 1996. [PUMA: biochem contg copper element enzyme essential review;protein review;review trace]

Wolfgang. Kaim. Thermal and light induced electron transfer reactions of Main Group metal hydrides and organometallics. Topics in Current Chemistry, (169)Electron Transfer I:231--251, 1994. [PUMA: Group Main electron hydride induced light review;organometallic review;review transfer]

Wolfgang Kaim, and Goutam Kumar. Lahiri. Unconventional mixed-valent complexes of ruthenium and osmium. Angewandte Chemie, International Edition, (46)11:1778--1796, 2007. [PUMA: bridged complex electron exchange intramol ligand mediated mixed osmium review review;review review;valence ruthenium transfer transfer;ruthenium valent]

W. Kaim, M. Moscherosch, S. Kohlmann, J. S. Field, and D. Fenske. Unusual stabilization of anion radicals by copper(I). Special Publication - Royal Society of Chemistry, (131)Chemistry of the Copper and Zinc Triads:248--251, 1993. [PUMA: anion azodicarboxylate copper phosphine radical review;crystal review;pyridylterazine review;review stabilization stabilized structure review;phenanthrolinesemidione]

O. J. Scherer, I. Bach, J. Schwalb, H. Sitzmann, G. Wolmershaeuser, W. Kaim, and R. Gross. Px Hueckel systems as complex ligands. Phosphorus and Sulfur and the Related Elements, (30)1-2:269--272, 1987. [PUMA: Hueckel ligand phosphorus polynuclear review;review]

Wolfgang Kaim, Wolfgang Bruns, Juergen Poppe, and Volker. Kasack. Spectroscopy of mixed valent states in dinuclear ions and metalloproteins. Journal of Molecular Structure, (292):221--228, 1993. [PUMA: ESR IR complex complex;UV mixed review review;metalloprotein review;review spectroscopy valence]

Wolfgang. Kaim. Heterocycles with 7 and 8p electrons. Models for flavin and pteridine intermediates and candidates for novel inorganic rings. Reviews of Chemical Intermediates, (8)3:247--286, 1987. [PUMA: flavin heterocycle review;pteridine review;review]

Wolfgang. Kaim. Many aspects of chemistry of 1,4-diazines: Organic, inorganic, and biochemical aspects. Angewandte Chemie, (95)3:201--221, 1983. [PUMA: annulated pyrazine review;review]

Wolfgang Kaim, Barbara Olbrich-Deussner, Renate Gross, Sylvia Ernst, Stephan Kohlmann, and Christian. Bessenbacher. Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes. NATO ASI Series, Series C: Mathematical and Physical Sciences, (257)Paramagn. Organomet. Species Act./Sel., Catal:283--294, 1989. [PUMA: anion complex electron formation metal reaction review;polynuclear review;review transfer transition]

Products from multiple insertion reactions between diisocyanates and antiheteroaromatic 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine: Organosilicon Chem. III, Muench. Silicontage, 3rd. In Torsten Sixt, Fridmann M. Hornung, Anja Ehlend, and Wolfgang. Kaim (Eds.), Wiley-VCH Verlag GmbH, 1998. [PUMA: antiheteroarom dihydropyrazine diisocyanate insertion isocyanate review;review silyl]

Wolfgang. Kaim. Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical. Science (Washington, DC, United States), (307)5707:216--217, 2005. [PUMA: aminyl biochem electron metal nitrogen odd prepn radical review;review stabilized]

Wolfgang. Kaim. Radical-forming electron-transfer reactions involving main-group organometallics. Accounts of Chemical Research, (18)6:160--166, 1985. [PUMA: electron generation organometallic radical review;review single transfer]

Wolfgang. Kaim. Coordinative aspects of single electron exchange between Main group or transition metal compounds and unsaturated organic substrates. Studies in Physical and Theoretical Chemistry, (78)Electron Proton Transfer Chem. Biol:45--69, 1992. [PUMA: Main electron exchange exchange;transition group metal organo review review;review single]

Wolfgang. Kaim. Coordinative aspects of single electron exchange between Main group or transition metal compounds and unsaturated organic substrates. Studies in Physical and Theoretical Chemistry, (78)Electron Proton Transfer Chem. Biol:45--69, 1992. [PUMA: Main electron exchange exchange;transition group metal organo review review;review single]

Wolfgang. Kaim. Radical-forming electron-transfer reactions involving main-group organometallics. Accounts of Chemical Research, (18)6:160--166, 1985. [PUMA: electron generation organometallic radical review;review single transfer]

Wolfgang. Kaim. Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical. Science (Washington, DC, United States), (307)5707:216--217, 2005. [PUMA: aminyl biochem electron metal nitrogen odd prepn radical review;review stabilized]

Products from multiple insertion reactions between diisocyanates and antiheteroaromatic 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine: Organosilicon Chem. III, Muench. Silicontage, 3rd. In Torsten Sixt, Fridmann M. Hornung, Anja Ehlend, and Wolfgang. Kaim (Eds.), Wiley-VCH Verlag GmbH, 1998. [PUMA: antiheteroarom dihydropyrazine diisocyanate insertion isocyanate review;review silyl]

Wolfgang Kaim, Barbara Olbrich-Deussner, Renate Gross, Sylvia Ernst, Stephan Kohlmann, and Christian. Bessenbacher. Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes. NATO ASI Series, Series C: Mathematical and Physical Sciences, (257)Paramagn. Organomet. Species Act./Sel., Catal:283--294, 1989. [PUMA: anion complex electron formation metal reaction review;polynuclear review;review transfer transition]

Wolfgang. Kaim. Many aspects of chemistry of 1,4-diazines: Organic, inorganic, and biochemical aspects. Angewandte Chemie, (95)3:201--221, 1983. [PUMA: annulated pyrazine review;review]

Wolfgang. Kaim. Heterocycles with 7 and 8p electrons. Models for flavin and pteridine intermediates and candidates for novel inorganic rings. Reviews of Chemical Intermediates, (8)3:247--286, 1987. [PUMA: flavin heterocycle review;pteridine review;review]

Wolfgang Kaim, Wolfgang Bruns, Juergen Poppe, and Volker. Kasack. Spectroscopy of mixed valent states in dinuclear ions and metalloproteins. Journal of Molecular Structure, (292):221--228, 1993. [PUMA: ESR IR complex complex;UV mixed review review;metalloprotein review;review spectroscopy valence]

O. J. Scherer, I. Bach, J. Schwalb, H. Sitzmann, G. Wolmershaeuser, W. Kaim, and R. Gross. Px Hueckel systems as complex ligands. Phosphorus and Sulfur and the Related Elements, (30)1-2:269--272, 1987. [PUMA: Hueckel ligand phosphorus polynuclear review;review]

W. Kaim, M. Moscherosch, S. Kohlmann, J. S. Field, and D. Fenske. Unusual stabilization of anion radicals by copper(I). Special Publication - Royal Society of Chemistry, (131)Chemistry of the Copper and Zinc Triads:248--251, 1993. [PUMA: anion azodicarboxylate copper phosphine radical review;crystal review;phenanthrolinesemidione review;pyridylterazine review;review stabilization stabilized structure]

Wolfgang Kaim, and Goutam Kumar. Lahiri. Unconventional mixed-valent complexes of ruthenium and osmium. Angewandte Chemie, International Edition, (46)11:1778--1796, 2007. [PUMA: bridged complex electron exchange intramol ligand mediated mixed osmium review review;review review;valence ruthenium transfer transfer;ruthenium valent]

Wolfgang. Kaim. Thermal and light induced electron transfer reactions of Main Group metal hydrides and organometallics. Topics in Current Chemistry, (169)Electron Transfer I:231--251, 1994. [PUMA: Group Main electron hydride induced light review;organometallic review;review transfer]

Wolfgang Kaim, and Jochen. Rall. Copper - A \dqmodern\dq bioelement. Angewandte Chemie, International Edition in English, (35)1:43--60, 1996. [PUMA: biochem contg copper element enzyme essential review;protein review;review trace]

Wolfgang. Kaim. The transition metal coordination chemistry of anion radicals. Coordination Chemistry Reviews, (76):187--235, 1987. [PUMA: anion carbon contg prepn property;spectra radical review review;complex review;nitrogen review;oxygen review;phosphorus review;review review;structure review;sulfur]

W. Kaim. Complexes with 2,2'-azobis(pyridine) and related 'S-frame' bridging ligands containing the azo function. Coordination Chemistry Reviews, (219-221):463--488, 2001. [PUMA: azobispyridine charge complex complex;structure intermediate metal review review;isomerism review;mixed review;oxidn review;radical review;review state transfer valence]

Mixed-valence intermediates as ideal targets for spectroelectrochemistry (SEC): Spectroelectrochem. In Wolfgang Kaim, Biprajit Sarkar, and Goutam Kumar. Lahiri (Eds.), Royal Society of Chemistry, 2008. [PUMA: ESR IR catalysis electrocatalysis intermediate mixed optical redox review;review spectroelectrochem valence vibrational]

Hans Bock, Wolfgang Kaim, A. Semkow, and Heinrich. Noeth. Chemistry of boron. 97. Radical ions. 17. Structure changes during the oxidation of boron-, carbon-, silicon-, or phosphorus-substituted hydrazines. Angewandte Chemie, (90)4:308--310, 1978. [PUMA: boron hydrazine ion;silicon radical review review;phosphorus review;review review;structure substituted]

Wolfgang. Kaim. Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical. Science (Washington, DC, United States), (307)5707:216--217, 2005. [PUMA: aminyl biochem electron metal nitrogen odd prepn radical review;review stabilized]