Compounds of silicon. 113. Sterically overloaded supersilyl compounds. 12. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: A new type of compound for a heavy Group 13 element. Angewandte Chemie, International Edition in English, (36)11:1213--1215, 1997. [PUMA: aluminum butylsilyl dinuclear gallium prepn prepn;crystal radical radical;ESR radical;gallium structure structure;silyl structure;supersilyl supersilyl]
Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E = B-In). Angewandte Chemie, International Edition, (40)3:566--568, 2001. [PUMA: alkyl cluster crystal gallium mol nonanuclear prepn structure]
Dithiocarbamates of gallium(III) and indium(III): Syntheses, spectroscopy, and structures. Polyhedron, (21)2:239--246, 2002. [PUMA: complex complex;dithiocarbamate crystal dithiocarbamate gallium indium prepn structure]
Ga9(CMe3)9.bul.--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium. Angewandte Chemie, International Edition, (42)21:2422--2423, 2003. [PUMA: alkyl anion butyl cluster crystal gallium mol prepn radical structure structure;tertiary]
Reactivity of \dqGaI\dq Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions. Organometallics, (21)15:3169--3172, 2002. [PUMA: B3LYP ESR calcn diazabutadiene diazabutadiene;heterocycle formation gallium heterocycle;crystal heterocycle;gallium in iodide mol monoanion paramagnetic prepn reaction situ spectra structure]
Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands. Organometallics, (19)6:1128--1131, 2000. [PUMA: bond bridging ferrocenedicarboxylate ferrocenedicarboxylate;gallium ferrocenedicarboxylate;oxidn gallium macrocycle macrocycle;crystal potential prepn structure structure;mol]
Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands. Organometallics, (19)6:1128--1131, 2000. [PUMA: bond bridging ferrocenedicarboxylate ferrocenedicarboxylate;gallium ferrocenedicarboxylate;oxidn gallium macrocycle macrocycle;crystal potential prepn structure structure;mol]
Reactivity of \dqGaI\dq Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions. Organometallics, (21)15:3169--3172, 2002. [PUMA: B3LYP ESR calcn diazabutadiene diazabutadiene;heterocycle formation gallium heterocycle;crystal heterocycle;gallium in iodide mol monoanion paramagnetic prepn reaction situ spectra structure]
Ga9(CMe3)9.bul.--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium. Angewandte Chemie, International Edition, (42)21:2422--2423, 2003. [PUMA: alkyl anion butyl cluster crystal gallium mol prepn radical structure structure;tertiary]
Dithiocarbamates of gallium(III) and indium(III): Syntheses, spectroscopy, and structures. Polyhedron, (21)2:239--246, 2002. [PUMA: complex complex;dithiocarbamate crystal dithiocarbamate gallium indium prepn structure]
Ga9(CMe3)9, an important new building block in the structural chemistry of the alkylelement(I) compounds EnRn (E = B-In). Angewandte Chemie, International Edition, (40)3:566--568, 2001. [PUMA: alkyl cluster crystal gallium mol nonanuclear prepn structure]
Compounds of silicon. 113. Sterically overloaded supersilyl compounds. 12. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: A new type of compound for a heavy Group 13 element. Angewandte Chemie, International Edition in English, (36)11:1213--1215, 1997. [PUMA: aluminum butylsilyl dinuclear gallium prepn prepn;crystal radical radical;ESR radical;gallium structure structure;silyl structure;supersilyl supersilyl]