%0 Journal Article %1 Dey.2004b %A Dey, Sandip %A Jain, Vimal K. %A Klein, Axel %A Kaim, Wolfgang. %D 2004 %J Inorganic Chemistry Communications %K aminopropylselenolate crystal dinuclear hexanuclear hexanuclear;palladium palladium prepn structure %N 5 %P 601--603 %R 10.1016/j.inoche.2004.02.005 %T Interconversion of structurally characterised complexes PdCl(Se-N)2 and Pd(Se-N)26 with the hemi-labile ligand Se-N = Me2NCH2CH2CH2Se- %V 7 %X The homoleptic hexanuclear palladium(II) selenolate Pd(SeCH2CH2CH2NMe2)26 (1) reacts readily with Na2PdCl4 to afford the binuclear PdCl(SeCH2CH2CH2NMe2)2 (2) and the latter can be converted back to 1 by treatment with NaSeCH2CH2CH2NMe2. The crystal structure of 1·2Me2CO was detd. The complex 1 has an hexagonal cyclo-PdSe26 center in which two palladium ions are always bridged by two selenolate Se atoms. on SciFinder(R)

@article{Dey.2004b, abstract = {The homoleptic hexanuclear palladium(II) selenolate [Pd(SeCH2CH2CH2NMe2)2]6 (1) reacts readily with Na2PdCl4 to afford the binuclear [PdCl(SeCH2CH2CH2NMe2)]2 (2) and the latter can be converted back to 1 by treatment with NaSeCH2CH2CH2NMe2. The crystal structure of 1·2Me2CO was detd. The complex 1 has an hexagonal cyclo-[PdSe2]6 center in which two palladium ions are always bridged by two selenolate Se atoms. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Dey, Sandip and Jain, Vimal K. and Klein, Axel and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/28e1ef9cbfb75bd32b3bd3d8f87acf602/huebleriac}, doi = {10.1016/j.inoche.2004.02.005}, interhash = {ebe1e1aa54481aead0e1dc83d5ad7d35}, intrahash = {8e1ef9cbfb75bd32b3bd3d8f87acf602}, issn = {1387-7003}, journal = {Inorganic Chemistry Communications}, keywords = {aminopropylselenolate crystal dinuclear hexanuclear hexanuclear;palladium palladium prepn structure}, number = 5, pages = {601--603}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Interconversion of structurally characterised complexes [PdCl(Se-N)]2 and [Pd(Se-N)2]6 with the hemi-labile ligand Se-N = Me2NCH2CH2CH2Se-}, volume = 7, year = 2004 }