%0 Journal Article %1 Uhl.2000 %A Uhl, Werner %A Spies, Thomas %A Haase, Detlev %A Winter, Rainer %A Kaim, Wolfgang. %D 2000 %J Organometallics %K bond bridging ferrocenedicarboxylate ferrocenedicarboxylate;gallium ferrocenedicarboxylate;oxidn gallium macrocycle macrocycle;crystal potential prepn structure structure;mol %N 6 %P 1128--1131 %R 10.1021/om990875q %T Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands %V 19 %X The reaction of tetrakis[bis(trimethylsilyl)methyl]digallane(4) with 1,1'-ferrocenedicarboxylic acid afforded 84\% orange-red crystals of the title macrocyclic compd. contg. a large 32-atom heterocycle, which comprises four Ga-Ga single bonds bridged by four 1,1'-ferrocenedicarboxylato ligands. The largest diam. of the mol. is $\sim$2.5 nm. The redox-active Ga-Ga sites and ferrocene Fe centers are all oxidized irreversibly within a narrow potential range. The structure of the macrocycle was detd. by x-ray crystallog. [on SciFinder(R)]

@article{Uhl.2000, abstract = {The reaction of tetrakis[bis(trimethylsilyl)methyl]digallane(4) with 1,1'-ferrocenedicarboxylic acid afforded 84{\%} orange-red crystals of the title macrocyclic compd. contg. a large 32-atom heterocycle, which comprises four Ga-Ga single bonds bridged by four 1,1'-ferrocenedicarboxylato ligands. The largest diam. of the mol. is $\sim$2.5 nm. The redox-active Ga-Ga sites and ferrocene Fe centers are all oxidized irreversibly within a narrow potential range. The structure of the macrocycle was detd. by x-ray crystallog. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Uhl, Werner and Spies, Thomas and Haase, Detlev and Winter, Rainer and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2abacf2b26172c20d4a79174594ce0940/huebleriac}, doi = {10.1021/om990875q}, interhash = {e5645e67b9788fac5de1e3101b258855}, intrahash = {abacf2b26172c20d4a79174594ce0940}, issn = {0276-7333}, journal = {Organometallics}, keywords = {bond bridging ferrocenedicarboxylate ferrocenedicarboxylate;gallium ferrocenedicarboxylate;oxidn gallium macrocycle macrocycle;crystal potential prepn structure structure;mol}, number = 6, pages = {1128--1131}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Synthesis of a Large Organometallic Macrocycle Comprising Four Ga-Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands}, volume = 19, year = 2000 }