%0 Journal Article %1 Sarkar.2005 %A Sarkar, Biprajit %A Patra, Srikanta %A Fiedler, Jan %A Sunoj, Raghavan B. %A Janardanan, Deepa %A Mobin, Shaikh M. %A Niemeyer, Mark %A Lahiri, Goutam Kumar %A Kaim, Wolfgang. %D 2005 %J Angewandte Chemie, International Edition %K acetylacetonate azobispyridine complex complex;electrochem complex;electronic complex;geometry complex;ruthenium crystal isomeric optimized prepn redox ruthenium structure %N 35 %P 5655--5658 %R 10.1002/anie.200501075 %T Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand %V 44 %X A unique kind of electronic structure (Mn+0.5)(m-L.bul.-)(Mn+0.5) which was previously discussed only for metal-ligand charge-transfer (MLCT) excited states is established structurally and by quantum chem. anal. for both rac and meso isomers of [(m-abpy)Ru(acac)22] (abpy = 2,2'-azobispyridine, acac- = acetylacetonate). [on SciFinder(R)]

@article{Sarkar.2005, abstract = {A unique kind of electronic structure (Mn+0.5)(\textgreek{m}-L.bul.-)(Mn+0.5) which was previously discussed only for metal-ligand charge-transfer (MLCT) excited states is established structurally and by quantum chem. anal. for both rac and meso isomers of [(\textgreek{m}-abpy){Ru(acac)2}2] (abpy = 2,2'-azobispyridine, acac- = acetylacetonate). [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Sarkar, Biprajit and Patra, Srikanta and Fiedler, Jan and Sunoj, Raghavan B. and Janardanan, Deepa and Mobin, Shaikh M. and Niemeyer, Mark and Lahiri, Goutam Kumar and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21119c8287c8cf0cb9a8cb36e6e848187/huebleriac}, doi = {10.1002/anie.200501075}, interhash = {e39395987a9d0f9479aa721991aaa134}, intrahash = {1119c8287c8cf0cb9a8cb36e6e848187}, issn = {1433-7851}, journal = {Angewandte Chemie, International Edition}, keywords = {acetylacetonate azobispyridine complex complex;electrochem complex;electronic complex;geometry complex;ruthenium crystal isomeric optimized prepn redox ruthenium structure}, number = 35, pages = {5655--5658}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand}, volume = 44, year = 2005 }