%0 Journal Article %1 holz2019generated %A Holz, Julia %A Pfeffer, Camilla %A Zuo, Hualiang %A Beierlein, Dennis %A Richter, Gunther %A Klemm, Elias %A Peters, René %B 30 %D 2019 %J Angewandte Chemie International Edition %K chemie für institut itcsend:unibiblio technische %P 10330-10334 %T In Situ Generated Gold Nanoparticles on Active Carbon as Reusable Highly Efficient Catalysts for a C −C Stille Coupling %U https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201902352 %V 58 %X Abstract Gold nanoparticle catalysts are important in many industrial production processes. Nevertheless, for traditional C −C cross-coupling reactions they have been rarely used and Pd catalysts usually give a superior performance. Herein we report that in situ formed gold metal nanoparticles are highly active catalysts for the cross coupling of allylstannanes and activated alkylbromides to form C −C bonds. Turnover numbers up to 29 000 could be achieved in the presence of active carbon as solid support, which allowed for convenient catalyst recovery and reuse. The present study is a rare case where a gold metal catalyst is superior to Pd catalysts in a cross-coupling reaction of an organic halide and an organometallic reagent.

@article{holz2019generated, abstract = {Abstract Gold nanoparticle catalysts are important in many industrial production processes. Nevertheless, for traditional C −C cross-coupling reactions they have been rarely used and Pd catalysts usually give a superior performance. Herein we report that in situ formed gold metal nanoparticles are highly active catalysts for the cross coupling of allylstannanes and activated alkylbromides to form C −C bonds. Turnover numbers up to 29 000 could be achieved in the presence of active carbon as solid support, which allowed for convenient catalyst recovery and reuse. The present study is a rare case where a gold metal catalyst is superior to Pd catalysts in a cross-coupling reaction of an organic halide and an organometallic reagent. }, added-at = {2019-08-27T15:11:22.000+0200}, author = {Holz, Julia and Pfeffer, Camilla and Zuo, Hualiang and Beierlein, Dennis and Richter, Gunther and Klemm, Elias and Peters, René}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2830af67ff3beedb5157d08acfbaca878/robinhimmelmann}, interhash = {d8ee714cca8aa98ad68ac79027b636a0}, intrahash = {830af67ff3beedb5157d08acfbaca878}, issn = {1433-7851}, journal = {Angewandte Chemie International Edition}, keywords = {chemie für institut itcsend:unibiblio technische}, pages = {10330-10334}, series = 30, timestamp = {2019-08-27T13:11:22.000+0200}, title = {In Situ Generated Gold Nanoparticles on Active Carbon as Reusable Highly Efficient Catalysts for a C −C Stille Coupling}, url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201902352}, volume = 58, year = 2019 }