%0 Journal Article %1 Das.2009b %A Das, Atanu Kumar %A Sarkar, Biprajit %A Duboc, Carole %A Strobel, Sabine %A Fiedler, Jan %A Zalis, Stanislav %A Lahiri, Goutam Kumar %A Kaim, Wolfgang. %D 2009 %J Angewandte Chemie, International Edition %K complex complex;cyclic complex;electronic complex;optimized complex;ruthenium crystal geometry iminobenzoquinone isomeric nitrosyl prepn ruthenium structure terpyridine voltammetry %N 23 %P 4242-4245, S4242/1-S4242/6 %R 10.1002/anie.200900767 %T An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands %V 48 %X Six combinations of oxidn. states are conceivable for the paramagnetic [Ruk(NOm)(Qn)(terpy)]2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: [Ruk(NOm)(Qn)(terpy)]2+ (k=2+, m=1+, n=1-). [on SciFinder(R)]

@article{Das.2009b, abstract = {Six combinations of oxidn. states are conceivable for the paramagnetic [Ruk(NOm)(Qn)(terpy)]2+ complex. Single-crystal X-ray diffraction, spectroscopic anal. (IR, EPR at conventional and high frequency), and DFT calcns. establish that it is the iminosemiquinone radical structure that is formed: [Ruk(NOm)(Qn)(terpy)]2+ (k=2+, m=1+, n=1-). [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Das, Atanu Kumar and Sarkar, Biprajit and Duboc, Carole and Strobel, Sabine and Fiedler, Jan and Zalis, Stanislav and Lahiri, Goutam Kumar and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d22407d0afc5f3452c1570c14b9c094c/huebleriac}, doi = {10.1002/anie.200900767}, interhash = {c6861d905bbb054759a66ba0689833a9}, intrahash = {d22407d0afc5f3452c1570c14b9c094c}, issn = {1433-7851}, journal = {Angewandte Chemie, International Edition}, keywords = {complex complex;cyclic complex;electronic complex;optimized complex;ruthenium crystal geometry iminobenzoquinone isomeric nitrosyl prepn ruthenium structure terpyridine voltammetry}, number = 23, pages = {4242-4245, S4242/1-S4242/6}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+ with Two Prototypical Non-Innocent Ligands}, volume = 48, year = 2009 }