Article,

The first structural characterization of an azoaromatic radical anion stabilized by dicopper(I) coordination

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Angewandte Chemie, International Edition, 37 (17): 2403--2404 (1998)
DOI: 10.1002/(SICI)1521-3773(19980918)37:17{\textless}2403::AID-ANIE2403{\textgreater}3.0.CO;2-J

Abstract

Newly prepd. 2,2'-azobis(5-chloropyrimidine) (abcp) reacts with [Cu(PPh3)4](PF6) to form [Cu(PPh3)2]2m-(abcp) (1) contg. an azoarom. radical anion, which was characterized by cyclic voltammetry, EPR and UV-vis measurements and x-ray crystal structure anal. [on SciFinder(R)]

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