%0 Journal Article %1 Kaim.1983d %A Kaim, Wolfgang %A Lubitz, Wolfgang. %D 1983 %J Angewandte Chemie %K ENDOR;electron bipyridine bipyridine;ENDOR bipyridine;boron borohydride complex coupling electron hyperfine lithium transfer triethyl triethylhydridoborate triethylhydridoborate;ESR triethylhydridoborate;TRIPLE %N 11 %P 915--916 %T Radical products in single electron transfer reactions of lithium triethylhydridoborate as detected by ESR and multinuclear (proton, boron-10, boron-11, and nitrogen-14) ENDOR spectroscopy %V 95 %X LiBHEt3 reacted with 4,4'-bipyridine (I) to give [I.2BEt3].bul.- and with 2,2'-bipyridine (II) to give [II.Li].bul., as shown by ESR. Hyperfine couplings in these complexes and in a pyrazine (III) complex, [III.2BEt3].bul.- were detd. by the ENDOR/TRIPLE method. Gross information about dipolar and quadrupolar interactions can also be obtained from temp.-dependent ENDOR intensities and linewidths. ENDOR resonance from 10B and 11B were detected for the 1st time because of their favorable relaxation behavior in these systems. [on SciFinder(R)]

@article{Kaim.1983d, abstract = {LiBHEt3 reacted with 4,4'-bipyridine (I) to give [I.2BEt3].bul.- and with 2,2'-bipyridine (II) to give [II.Li].bul., as shown by ESR. Hyperfine couplings in these complexes and in a pyrazine (III) complex, [III.2BEt3].bul.- were detd. by the ENDOR/TRIPLE method. Gross information about dipolar and quadrupolar interactions can also be obtained from temp.-dependent ENDOR intensities and linewidths. ENDOR resonance from 10B and 11B were detected for the 1st time because of their favorable relaxation behavior in these systems. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Lubitz, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2da76a517940dfff259fabfe06ef07e4a/huebleriac}, interhash = {bd11fb67bf9865898b89abb4db5a2e25}, intrahash = {da76a517940dfff259fabfe06ef07e4a}, issn = {0044-8249}, journal = {Angewandte Chemie}, keywords = {ENDOR;electron bipyridine bipyridine;ENDOR bipyridine;boron borohydride complex coupling electron hyperfine lithium transfer triethyl triethylhydridoborate triethylhydridoborate;ESR triethylhydridoborate;TRIPLE}, number = 11, pages = {915--916}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Radical products in single electron transfer reactions of lithium triethylhydridoborate as detected by ESR and multinuclear (proton, boron-10, boron-11, and nitrogen-14) ENDOR spectroscopy}, volume = 95, year = 1983 }