%0 Journal Article %1 Kaim.1985f %A Kaim, Wolfgang %A Kohlmann, Stephan. %D 1985 %J Inorganica Chimica Acta %K benzochalcogenadiazole benzochalcogenadiazole;tungsten carbonyl ditungsten potential redn %N 2 %P L21-L22 %R 10.1016/S0020-1693(00)85989-7 %T Coordination chemistry of p-electron deficient ligands. Binuclear tungsten pentacarbonyl complexes of the weakly basic 2,1,3-benzochalcogenadiazoles %V 101 %X LW(CO)52 (L = 2,1,3-benzochalcogenadiazole, chalcogen = O, S, Se) were prepd. by mixing W(CO)5(THF) and L in THF, removing the solvent, immediately redissolving the residue in toluene, and subsequently adding hexane. The complexes were characterized by chem. anal., cyclic voltammetry, and spectral (IR, 1H NMR, electronic) methods. L coordinates via the 2 N atoms to different W atoms. The ease of redn. of LW(CO)52 varies as Se \textgreater S \textgreater O. on SciFinder(R)

@article{Kaim.1985f, abstract = {L[W(CO)5]2 (L = 2,1,3-benzochalcogenadiazole, chalcogen = O, S, Se) were prepd. by mixing W(CO)5(THF) and L in THF, removing the solvent, immediately redissolving the residue in toluene, and subsequently adding hexane. The complexes were characterized by chem. anal., cyclic voltammetry, and spectral (IR, 1H NMR, electronic) methods. L coordinates via the 2 N atoms to different W atoms. The ease of redn. of L[W(CO)5]2 varies as Se {\textgreater} S {\textgreater} O. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Kohlmann, Stephan.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2df8ceeb55f17ee49001e4bd337223713/huebleriac}, doi = {10.1016/S0020-1693(00)85989-7}, interhash = {b3918b433b7b02e8a72638922b9c8ef7}, intrahash = {df8ceeb55f17ee49001e4bd337223713}, issn = {0020-1693}, journal = {Inorganica Chimica Acta}, keywords = {benzochalcogenadiazole benzochalcogenadiazole;tungsten carbonyl ditungsten potential redn}, number = 2, pages = {L21-L22}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Coordination chemistry of \textgreek{p}-electron deficient ligands. Binuclear tungsten pentacarbonyl complexes of the weakly basic 2,1,3-benzochalcogenadiazoles}, volume = 101, year = 1985 }