Abstract
M(CO)6 (M = Cr, W, Mo) react in THF with the radical anion I to give (CO)5M2L-. (M = Cr, Mo; L = I; X = O, S, Se; M = W; X = O, S) and (CO)5WL-. (X = Se). In (CO)5WL-., L is coordinated to W through the Se atom. The complexes were detected by ESR spectra. on SciFinder(R)
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