%0 Journal Article %1 Ye.2005d %A Ye, Shengfa %A Kaim, Wolfgang %A Niemeyer, Mark %A Hosmane, Narayan S. %D 2005 %J Organometallics %K bridging crystal cyclodimer methylplatinum methylthioquinoline methylthioquinoline;thiolate mol planar platinum prepn reaction;sulfidodimethyl redox structure transmethylation %N 5 %P 794--796 %R 10.1021/om049247l %T Stereospecific Intramolecular S$\rightarrow$Pt Transmethylation from 8-(Methylthio)quinoline to Coordinated PtMe2: Formation of syn-[fac-PtIVMe3(m-8-quinolinethiolato)]2 with Stacked Quinoline Rings %V 24 %X S to Pt(II) transmethylation was obsd. on reacting [PtMe2(m-SMe2)]2 or [PtMe2(m-SEt2)]2 with 8-(methylthio)quinoline (mtq) for extended periods of time or on heating of the isolable intermediate PtMe2(mtq). The final product, syn-[fac-PtMe3(m-qt)]2 (qt- = 8-quinolinethiolato), exhibits two quinoline rings in a nearly stacked arrangement. This internal redox reaction involving organometallic Pt constitutes a variant of the known Pt complex induced S-demethylation and proceeds in a stereospecific manner, as indicated by CD3 labeling expts. [on SciFinder(R)]

@article{Ye.2005d, abstract = {S to Pt(II) transmethylation was obsd. on reacting [PtMe2(\textgreek{m}-SMe2)]2 or [PtMe2(\textgreek{m}-SEt2)]2 with 8-(methylthio)quinoline (mtq) for extended periods of time or on heating of the isolable intermediate PtMe2(mtq). The final product, syn-[fac-PtMe3(\textgreek{m}-qt)]2 (qt- = 8-quinolinethiolato), exhibits two quinoline rings in a nearly stacked arrangement. This internal redox reaction involving organometallic Pt constitutes a variant of the known Pt complex induced S-demethylation and proceeds in a stereospecific manner, as indicated by CD3 labeling expts. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Ye, Shengfa and Kaim, Wolfgang and Niemeyer, Mark and Hosmane, Narayan S.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2500350600f8028118a423778d66344ae/huebleriac}, doi = {10.1021/om049247l}, interhash = {814f98c1d9bf7fa97432fa75cbf76295}, intrahash = {500350600f8028118a423778d66344ae}, issn = {0276-7333}, journal = {Organometallics}, keywords = {bridging crystal cyclodimer methylplatinum methylthioquinoline methylthioquinoline;thiolate mol planar platinum prepn reaction;sulfidodimethyl redox structure transmethylation}, number = 5, pages = {794--796}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Stereospecific Intramolecular S$\rightarrow$Pt Transmethylation from 8-(Methylthio)quinoline to Coordinated PtMe2: Formation of syn-[fac-PtIVMe3(\textgreek{m}-8-quinolinethiolato)]2 with Stacked Quinoline Rings}, volume = 24, year = 2005 }