%0 Journal Article %1 Dey.2003b %A Dey, Sandip %A Jain, Vimal K. %A Knoedler, Axel %A Kaim, Wolfgang. %D 2003 %J Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry %K NMR crystal methylaminoethylthiolate palladium phenylphosphine;methylaminoethylthiolate phosphine platinum prepn structure %N 9 %P 2339--2343 %T Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II) %V 42A %X Reaction of Na2PdCl4 with Me2NCH2CH2SH·HCl in MeOH affords trimeric PdCl(SCH2CH2NMe2)3. Treatment of M2Cl2(m-Cl)2(PR3)2 (M = Pd or Pt) with Me2NCH2CH2SH.HCl in the presence of NaHCO3 yields MCl(SCH2CH2NMe2)(PR3)n (n = 1 or 2). These complexes were isolated as monomeric species contg. chelating thiolate ligands. In some cases, with more basic phosphines; binuclear complexes (n = 2) contg. bridging thiolate ligands are also formed. All complexes were characterized by elemental anal. and NMR spectroscopy. The structure of PdCl(SCH2CH2NMe2)(PPh3) (2c) was established by x-ray crystallog. on SciFinder(R)

@article{Dey.2003b, abstract = {Reaction of Na2PdCl4 with Me2NCH2CH2SH·HCl in MeOH affords trimeric [PdCl(SCH2CH2NMe2)]3. Treatment of [M2Cl2(\textgreek{m}-Cl)2(PR3)2] (M = Pd or Pt) with Me2NCH2CH2SH.HCl in the presence of NaHCO3 yields [MCl(SCH2CH2NMe2)(PR3)]n (n = 1 or 2). These complexes were isolated as monomeric species contg. chelating thiolate ligands. In some cases, with more basic phosphines; binuclear complexes (n = 2) contg. bridging thiolate ligands are also formed. All complexes were characterized by elemental anal. and NMR spectroscopy. The structure of [PdCl(SCH2CH2NMe2)(PPh3)] (2c) was established by x-ray crystallog. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Dey, Sandip and Jain, Vimal K. and Knoedler, Axel and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/280f926e79f5c1b5ac1b2a99751f5ca51/huebleriac}, interhash = {4deef5192ff0a7a99e2a6109aa586ee5}, intrahash = {80f926e79f5c1b5ac1b2a99751f5ca51}, issn = {0376-4710}, journal = {Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical {\&} Analytical Chemistry}, keywords = {NMR crystal methylaminoethylthiolate palladium phenylphosphine;methylaminoethylthiolate phosphine platinum prepn structure}, number = 9, pages = {2339--2343}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II)}, volume = {42A}, year = 2003 }