%0 Journal Article %1 Pott.2002 %A Pott, Thomas %A Jutzi, Peter %A Kaim, Wolfgang %A Schoeller, Wolfgang W. %A Neumann, Beate %A Stammler, Anja %A Stammler, Hans-Georg %A Wanner, Matthias. %D 2002 %J Organometallics %K B3LYP ESR calcn diazabutadiene diazabutadiene;heterocycle formation gallium heterocycle;crystal heterocycle;gallium in iodide mol monoanion paramagnetic prepn reaction situ spectra structure %N 15 %P 3169--3172 %R 10.1021/om0200510 %T Reactivity of \dqGaI\dq Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions %V 21 %X The paramagnetic heterocycles N(R)C2H2N(R)GaI2 (R = 2,6-dimethylphenyl (1), 2,4,6-trimethylphenyl (2), and 2,6-diisopropylphenyl (3)) were obtained by reaction of \dqGaI\dq with Xyl-dab (N,N'-bis2,6-dimethylphenyl-1,4-diazabuta-1,3-diene), Mes-dab (N,N'-bis2,4,6-trimethylphenyl-1,4-diazabuta-1,3-diene), and Dipp-dab (N,N'-bis2,6-diisopropylphenyl-1,4-diazabuta-1,3-diene), resp. Compds. 1-3 were characterized structurally by x-ray crystallog. ESR investigations of 3 and quantum chem. calcns. for the parent system cyclic NHC2H2NHGaI2 were carried out to provide information on the bonding. The reaction of 1 with 1 equiv. of the 1,4-dilithiated Xyl-dab led to the formation of Ga(Xyl-dab)2 with one singly and one doubly reduced ligand; this compd. was also characterized by x-ray crystallog. on SciFinder(R)

@article{Pott.2002, abstract = {The paramagnetic heterocycles N(R)C2H2N(R)GaI2 (R = 2,6-dimethylphenyl (1), 2,4,6-trimethylphenyl (2), and 2,6-diisopropylphenyl (3)) were obtained by reaction of {\dq}GaI{\dq} with Xyl-dab (N,N'-bis[2,6-dimethylphenyl]-1,4-diazabuta-1,3-diene), Mes-dab (N,N'-bis[2,4,6-trimethylphenyl]-1,4-diazabuta-1,3-diene), and Dipp-dab (N,N'-bis[2,6-diisopropylphenyl]-1,4-diazabuta-1,3-diene), resp. Compds. 1-3 were characterized structurally by x-ray crystallog. ESR investigations of 3 and quantum chem. calcns. for the parent system [cyclic] NHC2H2NHGaI2 were carried out to provide information on the bonding. The reaction of 1 with 1 equiv. of the 1,4-dilithiated Xyl-dab led to the formation of Ga(Xyl-dab)2 with one singly and one doubly reduced ligand; this compd. was also characterized by x-ray crystallog. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Pott, Thomas and Jutzi, Peter and Kaim, Wolfgang and Schoeller, Wolfgang W. and Neumann, Beate and Stammler, Anja and Stammler, Hans-Georg and Wanner, Matthias.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2eac01077c3145af9779d6b78e5367d6f/huebleriac}, doi = {10.1021/om0200510}, interhash = {40014712787e595c456007fc485e15d4}, intrahash = {eac01077c3145af9779d6b78e5367d6f}, issn = {0276-7333}, journal = {Organometallics}, keywords = {B3LYP ESR calcn diazabutadiene diazabutadiene;heterocycle formation gallium heterocycle;crystal heterocycle;gallium in iodide mol monoanion paramagnetic prepn reaction situ spectra structure}, number = 15, pages = {3169--3172}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Reactivity of {\dq}GaI{\dq} Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions}, volume = 21, year = 2002 }