Article,

Mixed valency of a 5d element: The osmium example

, and .
Coordination Chemistry Reviews, 257 (9-10): 1650--1659 (2013)
DOI: 10.1016/j.ccr.2012.08.026

Abstract

A review. Pronounced spin-orbit coupling effects and the stabilization of higher oxidn. states for the osmium analogs of mixed-valent ruthenium compds. result in more complex electronic spectra, frequent EPR silence, and valence transfer-dependent comproportionation consts. for the intermediates. on SciFinder(R)

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