%0 Journal Article %1 Leboschka.2008 %A Leboschka, Markus %A Siegera, Monika %A Niemeyer, Mark %A Zalis, Stanislav %A Kaim, Wolfgang. %D 2008 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K dimer dimer;silver methylselenomethylbenzimidazole mol optimized prepn silver structure %N 12-13 %P 2343--2346 %R 10.1002/zaac.200800283 %T Dimerization of the 2-(methylselenomethyl)benzimidazole-silver(I) cation involving a AgI-AgI interaction %V 634 %X Reacting the bidentate ligand 2-(methylselenomethyl)-1H-benzimidazole (msb) with AgBF4 in CH3CN did not produce the expected Ag(msb)2+ ion with two five-membered chelate rings but the dimeric Ag2(msb)22+, isolated and crystd. from acetonitrile/methanol as Ag(msb)(CH3CN)2(BF4)2 with six-membered chelate rings Ag-Ag-Se-C-C-N involving a Ag-Ag bond of 3.156(1) \AA distance. DFT calcns. reproduce the obsd. mol. structure of the dication. on SciFinder(R)

@article{Leboschka.2008, abstract = {Reacting the bidentate ligand 2-(methylselenomethyl)-1H-benzimidazole (msb) with AgBF4 in CH3CN did not produce the expected [Ag(msb)2]+ ion with two five-membered chelate rings but the dimeric [Ag2(msb)2]2+, isolated and crystd. from acetonitrile/methanol as {[Ag(msb)(CH3CN)]2}(BF4)2 with six-membered chelate rings Ag-Ag-Se-C-C-N involving a Ag-Ag bond of 3.156(1) {\AA} distance. DFT calcns. reproduce the obsd. mol. structure of the dication. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Leboschka, Markus and Siegera, Monika and Niemeyer, Mark and Zalis, Stanislav and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/22a4821949f24897aeab26bc60299bbb3/huebleriac}, doi = {10.1002/zaac.200800283}, interhash = {2e5ee8755e1a3dc3f6d444da5eed9708}, intrahash = {2a4821949f24897aeab26bc60299bbb3}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {dimer dimer;silver methylselenomethylbenzimidazole mol optimized prepn silver structure}, number = {12-13}, pages = {2343--2346}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Dimerization of the 2-(methylselenomethyl)benzimidazole-silver(I) cation involving a AgI-AgI interaction}, volume = 634, year = 2008 }