%0 Journal Article %1 Roth.1992 %A Roth, Thomas %A Kaim, Wolfgang. %D 1992 %J Inorganic Chemistry %K carbonyl complex cyanoethylene electrochem redn tungsten %N 10 %P 1930--1933 %R 10.1021/ic00036a038 %T Electron-transfer-induced isomerization h2(C:C) $\rightarrow$ h1(N) of the tetracyanoethylene complex, pentacarbonyl(tetracyanoethylene)tungsten (0/1-) %V 31 %X Single-electron transfer to the p (C:C)-bonded tetracyanoethylene (TCNE) ligand in the blue complex with W(CO)5 leads to a yellow isomerized anion radical product in which TCNE- coordinates via one nitrile N lone pair. The high-resoln. EPR, UV/visible and IR data of the singly reduced complex clearly illustrate the lowered symmetry and diminished p-back-donation in the anionic form. Cyclic voltammetric expts. at variable scan rates show two distinctly sep. second redn. processes of the n- and s-coordinated complexes in what appears to be an organometallic example of mol. hysteresis (Sano, M. and Taube 1991). [on SciFinder(R)]

@article{Roth.1992, abstract = {Single-electron transfer to the \textgreek{p} (C:C)-bonded tetracyanoethylene (TCNE) ligand in the blue complex with W(CO)5 leads to a yellow isomerized anion radical product in which TCNE- coordinates via one nitrile N lone pair. The high-resoln. EPR, UV/visible and IR data of the singly reduced complex clearly illustrate the lowered symmetry and diminished \textgreek{p}-back-donation in the anionic form. Cyclic voltammetric expts. at variable scan rates show two distinctly sep. second redn. processes of the n- and \textgreek{s}-coordinated complexes in what appears to be an organometallic example of mol. hysteresis (Sano, M. and Taube 1991). [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Roth, Thomas and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2250cc8807898f9f996ee6a573bd55a78/huebleriac}, doi = {10.1021/ic00036a038}, interhash = {2ca0cf319a6de5f117eb4d0d37916274}, intrahash = {250cc8807898f9f996ee6a573bd55a78}, issn = {0020-1669}, journal = {Inorganic Chemistry}, keywords = {carbonyl complex cyanoethylene electrochem redn tungsten}, number = 10, pages = {1930--1933}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Electron-transfer-induced isomerization \textgreek{h}2(C:C) $\rightarrow$ \textgreek{h}1(N) of the tetracyanoethylene complex, pentacarbonyl(tetracyanoethylene)tungsten (0/1-)}, volume = 31, year = 1992 }