A new non-innocent ligand redox system, N,N'-bis(4-dimethylaminophenyl) substituted acetamidinato/acetamidinyl, has been designed and described by example of structurally and spectroscopically characterized ruthenium complexes. The hitherto unreported ligand is responsible for rather intense and narrow absorptions in the near-IR region of the one- and two-electron oxidized forms. The spectroscopic, computational, and first structural characterization of an amidinyl radical complex adds to the list of established N-based radical ligands. on SciFinder(R)
%0 Journal Article
%1 Ehret.2015
%A Ehret, Fabian
%A Bubrin, Martina
%A Zalis, Stanislav
%A Kaim, Wolfgang.
%D 2015
%J Chemistry - A European Journal
%K complex dye ligand mol prepn redox ruthenium structure
%N 35
%P 12275--12278
%R 10.1002/chem.201501875
%T Metal-Chelating N,N'-Bis(4-dimethylaminophenyl)acetamidinyl Radical: A New Chromophore for the Near-Infrared Region
%V 21
%X A new non-innocent ligand redox system, N,N'-bis(4-dimethylaminophenyl) substituted acetamidinato/acetamidinyl, has been designed and described by example of structurally and spectroscopically characterized ruthenium complexes. The hitherto unreported ligand is responsible for rather intense and narrow absorptions in the near-IR region of the one- and two-electron oxidized forms. The spectroscopic, computational, and first structural characterization of an amidinyl radical complex adds to the list of established N-based radical ligands. on SciFinder(R)
@article{Ehret.2015,
abstract = {A new non-innocent ligand redox system, N,N'-bis(4-dimethylaminophenyl) substituted acetamidinato/acetamidinyl, has been designed and described by example of structurally and spectroscopically characterized ruthenium complexes. The hitherto unreported ligand is responsible for rather intense and narrow absorptions in the near-IR region of the one- and two-electron oxidized forms. The spectroscopic, computational, and first structural characterization of an amidinyl radical complex adds to the list of established N-based radical ligands. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Ehret, Fabian and Bubrin, Martina and Zalis, Stanislav and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2b26a3e0c66ccb8841612a2c583b65f8b/b_schwederski},
doi = {10.1002/chem.201501875},
interhash = {bdffc5f4e1bbc80aa38b6f608805d0a2},
intrahash = {b26a3e0c66ccb8841612a2c583b65f8b},
issn = {0947-6539},
journal = {Chemistry - A European Journal},
keywords = {complex dye ligand mol prepn redox ruthenium structure},
number = 35,
pages = {12275--12278},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Metal-Chelating N,N'-Bis(4-dimethylaminophenyl)acetamidinyl Radical: A New Chromophore for the Near-Infrared Region},
volume = 21,
year = 2015
}
