Abstract We report the simple one-pot synthesis of size tunable zinc oxide nanoparticles (ZnO NPs) out of an organometallic ZnO precursor using the self-assembly of solution phase polystyrene-block-poly(2-vinylpyridine) micelles. The resulting hybrid material could be deposited on various substrates in a straightforward manner with the NPs showing size-dependent absorption and photoluminescence due to the quantum-size effect. We compare the results to the assembly of preformed NPs which are selectively incorporated in the poly(2-vinylpyridine) core of the micelles due to the high affinity of ZnO to vinylpyridine.
%0 Journal Article
%1 braun2010block
%A Braun, C. H.
%A Richter, T. V.
%A Schacher, F.
%A Müller, A. H. E.
%A Crossland, E. J. W.
%A Ludwigs, S.
%B Macromolecular Rapid Communications
%D 2010
%I John Wiley & Sons, Ltd
%J Macromolecular Rapid Communications
%K ipoc-fp
%N 8
%P 729
%R https://doi.org/10.1002/marc.200900798
%T Block Copolymer Micellar Nanoreactors for the Directed Synthesis of ZnO Nanoparticles.
%U https://doi.org/10.1002/marc.200900798
%V 31
%X Abstract We report the simple one-pot synthesis of size tunable zinc oxide nanoparticles (ZnO NPs) out of an organometallic ZnO precursor using the self-assembly of solution phase polystyrene-block-poly(2-vinylpyridine) micelles. The resulting hybrid material could be deposited on various substrates in a straightforward manner with the NPs showing size-dependent absorption and photoluminescence due to the quantum-size effect. We compare the results to the assembly of preformed NPs which are selectively incorporated in the poly(2-vinylpyridine) core of the micelles due to the high affinity of ZnO to vinylpyridine.
@article{braun2010block,
abstract = {Abstract We report the simple one-pot synthesis of size tunable zinc oxide nanoparticles (ZnO NPs) out of an organometallic ZnO precursor using the self-assembly of solution phase polystyrene-block-poly(2-vinylpyridine) micelles. The resulting hybrid material could be deposited on various substrates in a straightforward manner with the NPs showing size-dependent absorption and photoluminescence due to the quantum-size effect. We compare the results to the assembly of preformed NPs which are selectively incorporated in the poly(2-vinylpyridine) core of the micelles due to the high affinity of ZnO to vinylpyridine.},
added-at = {2022-11-17T10:55:57.000+0100},
author = {Braun, C. H. and Richter, T. V. and Schacher, F. and Müller, A. H. E. and Crossland, E. J. W. and Ludwigs, S.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/28cf562d44f499eac296f7c98b206c89d/bomiecienski},
booktitle = {Macromolecular Rapid Communications},
comment = {https://doi.org/10.1002/marc.200900798},
doi = {https://doi.org/10.1002/marc.200900798},
interhash = {f538395ad7aa300cd622a93267e9c275},
intrahash = {8cf562d44f499eac296f7c98b206c89d},
issn = {10221336},
journal = {Macromolecular Rapid Communications},
keywords = {ipoc-fp},
month = {4},
number = 8,
pages = 729,
publisher = {John Wiley & Sons, Ltd},
timestamp = {2023-05-15T12:50:46.000+0200},
title = {Block Copolymer Micellar Nanoreactors for the Directed Synthesis of ZnO Nanoparticles.},
url = {https://doi.org/10.1002/marc.200900798},
volume = 31,
year = 2010
}