%0 Journal Article %1 Bock.1984 %A Bock, Hans %A Kaim, Wolfgang %A Kira, Mitsuo %A Rene, Louis %A Viehe, Heinz Guenther. %D 1984 %J Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie %K acetylene amino bisdialkylamino cation cation;allene dialkylamino ethylene oxidn;ESR oxidn;aminoacetylene radical %N 6 %P 763--770 %T Radical ions, 61. Dialkylamino-substituted acetylenes and allenes: Ionization, oxidation, and aluminum chloride-catalyzed hydrogen transfer %V 39B %X Photoelectron spectra of R2NC$\equiv$CNR2 and of (R2N)2C:C:C(NR2)2 (I; R = Me, Et) exhibit halves twisted against each other. The low 1st ionization potentials at 7.0-7.7 eV stimulated attempts to oxidize using AlCl3 in CH2Cl2 or CD2Cl2. The hyperfine-structured ESR spectra obsd. can be assigned unequivocally to the ethylene radical cations R2NHC:CHNR2.bul.+, which are formed from the obviously nonpersistent species R2NC$\equiv$CNR2.bul.+ via H transfer. No paramagnetic intermediates were detected during I oxidn., presumably owing to rapid dimerization of (R2N)2C:C:C(NR2)2.bul.+. on SciFinder(R)

@article{Bock.1984, abstract = {Photoelectron spectra of R2NC$\equiv$CNR2 and of (R2N)2C:C:C(NR2)2 (I; R = Me, Et) exhibit halves twisted against each other. The low 1st ionization potentials at 7.0-7.7 eV stimulated attempts to oxidize using AlCl3 in CH2Cl2 or CD2Cl2. The hyperfine-structured ESR spectra obsd. can be assigned unequivocally to the ethylene radical cations R2NHC:CHNR2.bul.+, which are formed from the obviously nonpersistent species R2NC$\equiv$CNR2.bul.+ via H transfer. No paramagnetic intermediates were detected during I oxidn., presumably owing to rapid dimerization of (R2N)2C:C:C(NR2)2.bul.+. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Bock, Hans and Kaim, Wolfgang and Kira, Mitsuo and Rene, Louis and Viehe, Heinz Guenther.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27193050f0226706b1d499f3c375b2322/huebleriac}, interhash = {8a0e695d4c03ede298ba6d511c9cc08d}, intrahash = {7193050f0226706b1d499f3c375b2322}, issn = {0340-5087}, journal = {Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie}, keywords = {acetylene amino bisdialkylamino cation cation;allene dialkylamino ethylene oxidn;ESR oxidn;aminoacetylene radical}, number = 6, pages = {763--770}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Radical ions, 61. Dialkylamino-substituted acetylenes and allenes: Ionization, oxidation, and aluminum chloride-catalyzed hydrogen transfer}, volume = {39B}, year = 1984 }